151
Pipeline and Haz. Matls. Safety Admin., DOT
Pt. 172
172 of this subchapter pertaining to
shipping papers and placarding, and
otherwise conforms to the applicable
requirements of part 176 of this sub-
chapter.
(2) The requirement in § 172.201(d) of
this subchapter for an emergency tele-
phone number does not apply to ship-
ments made in accordance with the
IMDG Code if the hazardous material is
not offloaded from the vessel, or is
offloaded between ocean vessels at a
U.S. port facility without being trans-
ported by public highway.
[72 FR 25172, May 3, 2007, as amended at 72
FR 44847, Aug. 9, 2007; 73 FR 57004, Oct. 1,
2008; 74 FR 2233, Jan. 14, 2009; 76 FR 3345, Jan.
19, 2011; 79 FR 46034, Aug. 6, 2014; 80 FR 1116,
Jan. 8, 2015; 87 FR 78010, Dec. 21, 2022]
§ 171.26
Additional requirements for
the use of the IAEA Regulations.
A Class 7 (radioactive) material being
imported into or exported from the
United States or passing through the
United States in the course of being
shipped between places outside the
United States may be offered for trans-
portation or transported in accordance
with the IAEA Regulations (IBR, see
§ 171.7) as authorized in paragraph (a) of
§ 171.22, provided the requirements in
§ 171.22, as applicable, are met.
PART 172—HAZARDOUS MATERIALS
TABLE, SPECIAL PROVISIONS,
HAZARDOUS MATERIALS COM-
MUNICATIONS, EMERGENCY RE-
SPONSE INFORMATION, TRAIN-
ING REQUIREMENTS, AND SECU-
RITY PLANS
Subpart A—General
Sec.
172.1
Purpose and scope.
172.3
Applicability.
Subpart B—Table of Hazardous Materials
and Special Provisions
172.101
Purpose and use of hazardous mate-
rials table.
172.102
Special provisions.
Subpart C—Shipping Papers
172.200
Applicability.
172.201
Preparation and retention of ship-
ping papers.
172.202
Description of hazardous material on
shipping papers.
172.203
Additional description requirements.
172.204
Shipper’s certification.
172.205
Hazardous waste manifest.
Subpart D—Marking
172.300
Applicability.
172.301
General marking requirements for
non-bulk packagings.
172.302
General marking requirements for
bulk packagings.
172.303
Prohibited marking.
172.304
Marking requirements.
172.306
[Reserved]
172.308
Authorized abbreviations.
172.310
Class 7 (radioactive) materials.
172.312
Liquid hazardous materials in non-
bulk packagings.
172.313
Poisonous hazardous materials.
172.315
Limited quantities.
172.316
[Reserved]
172.317
KEEP AWAY FROM HEAT handling
mark.
172.320
Explosive hazardous materials.
172.322
Marine pollutants.
172.323
Infectious substances.
172.324
Hazardous substances in non-bulk
packagings.
172.325
Elevated temperature materials.
172.326
Portable tanks.
172.327
Petroleum sour crude oil in bulk
packaging.
172.328
Cargo tanks.
172.330
Tank cars and multi-unit tank car
tanks.
172.331
Bulk packagings other than portable
tanks, cargo tanks, tank cars and multi-
unit tank car tanks.
172.332
Identification number markings.
172.334
Identification numbers; prohibited
display.
172.336
Identification numbers; special pro-
visions.
172.338
Replacement of identification num-
bers.
Subpart E—Labeling
172.400
General labeling requirements.
172.400a
Exceptions from labeling.
172.401
Prohibited labeling.
172.402
Additional labeling requirements.
172.403
Class 7 (radioactive) material.
172.404
Labels for mixed and consolidated
packaging.
172.405
Authorized label modifications.
172.406
Placement of labels.
172.407
Label specifications.
172.411
EXPLOSIVE 1.1, 1.2, 1.3, 1.4, 1.5 and
1.6 labels, and EXPLOSIVE Subsidiary
label.
172.415
NON-FLAMMABLE GAS label.
172.416
POISON GAS label.
172.417
FLAMMABLE GAS label.
172.419
FLAMMABLE LIQUID label.
152
49 CFR Ch. I (10–1–23 Edition)
§ 172.1
172.420
FLAMMABLE SOLID label.
172.422
SPONTANEOUSLY COMBUSTIBLE
label.
172.423
DANGEROUS WHEN WET label.
172.426
OXIDIZER label.
172.427
ORGANIC PEROXIDE label.
172.429
POISON INHALATION HAZARD
label.
172.430
POISON label.
172.431
[Reserved]
172.432
INFECTIOUS SUBSTANCE label.
172.436
RADIOACTIVE WHITE-I label.
172.438
RADIOACTIVE YELLOW-II label.
172.440
RADIOACTIVE YELLOW-III label.
172.441
FISSILE label.
172.442
CORROSIVE label.
172.444
[Reserved]
172.446
CLASS 9 label.
172.447
LITHIUM BATTERY label.
172.448
CARGO AIRCRAFT ONLY label.
172.450
EMPTY label.
Subpart F—Placarding
172.500
Applicability of placarding require-
ments.
172.502
Prohibited and permissive
placarding.
172.503
Identification number display on
placards.
172.504
General placarding requirements.
172.505
Placarding for subsidiary hazards.
172.506
Providing and affixing placards:
Highway.
172.507
Special placarding provisions: High-
way.
172.508
Placarding and affixing placarding:
Rail.
172.510
Special placarding provisions: Rail.
172.512
Freight containers and aircraft unit
load devices.
172.514
Bulk packagings.
172.516
Visibility and display of placards.
172.519
General specifications for placards.
172.521
DANGEROUS placard.
172.522
EXPLOSIVES 1.1, EXPLOSIVES 1.2
and EXPLOSIVES 1.3 placards.
172.523
EXPLOSIVES 1.4 placard.
172.524
EXPLOSIVES 1.5 placard.
172.525
EXPLOSIVES 1.6 placard.
172.526
[Reserved]
172.527
Background requirements for cer-
tain placards.
172.528
NON-FLAMMABLE GAS placard.
172.530
OXYGEN placard.
172.532
FLAMMABLE GAS placard.
172.536
[Reserved]
172.540
POISON GAS placard.
172.542
FLAMMABLE placard.
172.544
COMBUSTIBLE placard.
172.546
FLAMMABLE SOLID placard.
172.547
SPONTANEOUSLY COMBUSTIBLE
placard.
172.548
DANGEROUS WHEN WET placard.
172.550
OXIDIZER placard.
172.552
ORGANIC PEROXIDE placard.
172.553
[Reserved]
172.554
POISON placard.
172.555
POISON INHALATION HAZARD
placard.
172.556
RADIOACTIVE placard.
172.558
CORROSIVE placard.
172.560
CLASS 9 placard.
Subpart G—Emergency Response
Information
172.600
Applicability and general require-
ments.
172.602
Emergency response information.
172.604
Emergency response telephone num-
ber.
172.606
Carrier information contact.
Subpart H—Training
172.700
Purpose and scope.
172.701
Federal-State relationship.
172.702
Applicability and responsibility for
training and testing.
172.704
Training requirements.
Subpart I—Safety and Security Plans
172.800
Purpose and applicability.
172.802
Components of a security plan.
172.804
Relationship to other Federal re-
quirements.
172.820
Additional planning requirements
for transportation by rail.
172.822
Limitation on actions by states,
local governments, and Indian tribes.
A
PPENDIX
A
TO
P
ART
172—O
FFICE OF
H
AZ
-
ARDOUS
M
ATERIALS
T
RANSPORTATION
C
OLOR
T
OLERANCE
C
HARTS AND
T
ABLES
A
PPENDIX
B
TO
P
ART
172—T
REFOIL
S
YMBOL
A
PPENDIX
C
TO
P
ART
172—D
IMENSIONAL
S
PEC
-
IFICATIONS
FOR
R
ECOMMENDED
P
LACARD
H
OLDER
A
PPENDIX
D
TO
P
ART
172—R
AIL
R
ISK
A
NAL
-
YSIS
F
ACTORS
A
UTHORITY
: 49 U.S.C. 5101–5128, 44701; 49
CFR 1.81, 1.96 and 1.97.
S
OURCE
: Amdt. 172–29, 41 FR 15996, Apr. 15,
1976, unless otherwise noted.
Subpart A—General
§ 172.1
Purpose and scope.
This part lists and classifies those
materials which the Department has
designated as hazardous materials for
purposes of transportation and pre-
scribes the requirements for shipping
papers, package marking, labeling, and
transport vehicle placarding applicable
to the shipment and transportation of
those hazardous materials.
[Amdt. 172–29, 41 FR 15997, Apr. 15, 1976, as
amended by 66 FR 45379, Aug. 28, 2001]
153
Pipeline and Haz. Matls. Safety Admin., DOT
§ 172.101
§ 172.3
Applicability.
(a) This part applies to—
(1) Each person who offers a haz-
ardous material for transportation, and
(2) Each carrier by air, highway, rail,
or water who transports a hazardous
material.
(b) When a person, other than one of
those provided for in paragraph (a) of
this section, performs a packaging la-
beling or marking function required by
this part, that person shall perform the
function in accordance with this part.
[Amdt. 172–29, 41 FR 15996, Apr. 15, 1976, as
amended by Amdt. 172–32, 41 FR 38179, Sept.
9, 1976]
Subpart B—Table of Hazardous
Materials and Special Provisions
§ 172.101
Purpose and use of haz-
ardous materials table.
(a) The Hazardous Materials Table
(Table) in this section designates the
materials listed therein as hazardous
materials for the purpose of transpor-
tation of those materials. For each
listed material, the Table identifies the
hazard class or specifies that the mate-
rial is forbidden in transportation, and
gives the proper shipping name or di-
rects the user to the preferred proper
shipping name. In addition, the Table
specifies or references requirements in
this subchapter pertaining to labeling,
packaging, quantity limits aboard air-
craft and stowage of hazardous mate-
rials aboard vessels.
(b)
Column 1: Symbols.
Column 1 of the
Table contains six symbols (‘‘ + ’’, ‘‘A’’,
‘‘D’’, ‘‘G’’, ‘‘I’’ and ‘‘W’’) as follows:
(1) The plus (+) sign fixes the proper
shipping name, hazard class and pack-
ing group for that entry without regard
to whether the material meets the defi-
nition of that class, packing group or
any other hazard class definition. When
the plus sign is assigned to a proper
shipping name in Column (1) of the
§ 172.101 Table, it means that the mate-
rial is known to pose a risk to humans.
When a plus sign is assigned to mix-
tures or solutions containing a mate-
rial where the hazard to humans is sig-
nificantly different from that of the
pure material or where no hazard to
humans is posed, the material may be
described using an alternative shipping
name that represents the hazards posed
by the material. An appropriate alter-
nate proper shipping name and hazard
class may be authorized by the Asso-
ciate Administrator.
(2) The letter ‘‘A’’ denotes a material
that is subject to the requirements of
this subchapter only when offered or
intended for transportation by aircraft,
unless the material is a hazardous sub-
stance or a hazardous waste. A ship-
ping description entry preceded by an
‘‘A’’ may be used to describe a material
for other modes of transportation pro-
vided all applicable requirements for
the entry are met.
(3) The letter ‘‘D’’ identifies proper
shipping names which are appropriate
for describing materials for domestic
transportation but may be inappro-
priate for international transportation
under the provisions of international
regulations (e.g., IMO, ICAO). An alter-
nate proper shipping name may be se-
lected when either domestic or inter-
national transportation is involved.
(4) The letter ‘‘G’’ identifies proper
shipping names for which one or more
technical names of the hazardous ma-
terial must be entered in parentheses,
in association with the basic descrip-
tion. (See § 172.203(k).)
(5) The letter ‘‘I’’ identifies proper
shipping names which are appropriate
for describing materials in inter-
national transportation. An alternate
proper shipping name may be selected
when only domestic transportation is
involved.
(6) The letter ‘‘W’’ denotes a material
that is subject to the requirements of
this subchapter only when offered or
intended for transportation by vessel,
unless the material is a hazardous sub-
stance or a hazardous waste. A ship-
ping description entry preceded by a
‘‘W’’ may be used to describe a mate-
rial for other modes of transportation
provided all applicable requirements
for the entry are met.
(c)
Column 2: Hazardous materials de-
scriptions and proper shipping names.
Column 2 lists the hazardous materials
descriptions and proper shipping names
of materials designated as hazardous
materials. Modification of a proper
shipping name may otherwise be re-
quired or authorized by this section.
Proper shipping names are limited to
154
49 CFR Ch. I (10–1–23 Edition)
§ 172.101
those shown in Roman type (not
italics).
(1) Proper shipping names may be
used in the singular or plural and in ei-
ther capital or lower case letters.
Words may be alternatively spelled in
the same manner as they appear in the
ICAO Technical Instructions or the
IMDG Code. For example ‘‘aluminum’’
may be spelled ‘‘aluminium’’ and ‘‘sul-
fur’’ may be spelled ‘‘sulphur’’. How-
ever, the word ‘‘inflammable’’ may not
be used in place of the word ‘‘flam-
mable’’.
(2) Punctuation marks and words in
italics are not part of the proper ship-
ping name, but may be used in addition
to the proper shipping name. The word
‘‘or’’ in italics indicates that there is a
choice of terms in the sequence that
may alternately be used as the proper
shipping name or as part of the proper
shipping name, as appropriate. For ex-
ample, for the hazardous materials de-
scription ‘‘Carbon dioxide, solid or Dry
ice’’ either ‘‘Carbon dioxide, solid’’ or
‘‘Dry ice’’ may be used as the proper
shipping name; and for the hazardous
materials description ‘‘Articles, pres-
surized pneumatic or hydraulic,’’ ei-
ther ‘‘Articles, pressurized pneumatic’’
or ‘‘Articles, pressurized hydraulic’’
may be used as the proper shipping
name.
(3) The word ‘‘poison’’ or ‘‘poisonous’’
may be used interchangeably with the
word ‘‘toxic’’ when only domestic
transportation is involved. The abbre-
viation ‘‘n.o.i.’’ or ‘‘n.o.i.b.n.’’ may be
used interchangeably with ‘‘n.o.s.’’.
(4) Except for hazardous wastes, when
qualifying words are used as part of the
proper shipping name, their sequence
in the package markings and shipping
paper description is optional. However,
the entry in the Table reflects the pre-
ferred sequence.
(5) When one entry references an-
other entry by use of the word ‘‘see’’, if
both names are in Roman type, either
name may be used as the proper ship-
ping name (e.g., Ethyl alcohol,
see
Eth-
anol).
(6) When a proper shipping name in-
cludes a concentration range as part of
the shipping description, the actual
concentration, if it is within the range
stated, may be used in place of the con-
centration range. For example, an
aqueous solution of hydrogen peroxide
containing 30 percent peroxide may be
described as ‘‘Hydrogen peroxide, aque-
ous solution
with not less than 20 percent
but not more than 40 percent hydrogen
peroxide’’
or ‘‘Hydrogen peroxide, aque-
ous solution
with 30 percent hydrogen
peroxide.
’’ Also, the percent sign (%)
may be used in place of the word ‘‘per-
cent’’ when words in italics containing
the word ‘‘percent’’ are used in addi-
tion to the proper shipping name.
(7) Use of the prefix ‘‘mono’’ is op-
tional in any shipping name, when ap-
propriate. Thus, Iodine monochloride
may be used interchangeably with Io-
dine chloride. In ‘‘Glycerol alpha-
monochlorohydrin’’ the term ‘‘mono’’
is considered a prefix to the term
‘‘chlorohydrin’’ and may be deleted.
(8) Use of the word ‘‘liquid’’ or
‘‘solid’’. The word ‘‘liquid’’ or ‘‘solid’’
may be added to a proper shipping
name when a hazardous material spe-
cifically listed by name may, due to
differing physical states, be a liquid or
solid. When the packaging specified in
Column 8 is inappropriate for the phys-
ical state of the material, the table
provided in paragraph (i)(4) of this sec-
tion should be used to determine the
appropriate packaging section.
(9)
Hazardous wastes.
If the word
‘‘waste’’ is not included in the haz-
ardous material description in Column
2 of the Table, the proper shipping
name for a hazardous waste (as defined
in § 171.8 of this subchapter), shall in-
clude the word ‘‘Waste’’ preceding the
proper shipping name of the material.
For example: Waste acetone.
(10)
Mixtures and solutions.
(i) A mix-
ture or solution meeting the definition
of one or more hazard class that is not
identified specifically by name, com-
prised of a single predominant haz-
ardous material identified in the Table
by technical name and one or more
hazardous and/or non-hazardous mate-
rial, must be described using the proper
shipping name of the hazardous mate-
rial and the qualifying word ‘‘mixture’’
or ‘‘solution’’, as appropriate, unless—
(A) Except as provided in
§ 172.101(i)(4) the packaging specified in
Column 8 is inappropriate to the phys-
ical state of the material;
(B) The shipping description indi-
cates that the proper shipping name
155
Pipeline and Haz. Matls. Safety Admin., DOT
§ 172.101
applies only to the pure or technically
pure hazardous material;
(C) The hazard class, packing group,
or subsidiary hazard of the mixture or
solution is different from that specified
for the entry;
(D) There is a significant change in
the measures to be taken in emer-
gencies;
(E) The material is identified by spe-
cial provision in Column 7 of the
§ 172.101 Table as a material poisonous
by inhalation; however, it no longer
meets the definition of poisonous by in-
halation or it falls within a different
hazard zone than that specified in the
special provision; or
(F) The material can be appro-
priately described by a shipping name
that describes its intended application,
such as ‘‘Coating solution’’, ‘‘Extracts,
flavoring’’ or ‘‘Compound, cleaning liq-
uid.’’.
(ii) If one or more of the conditions
in paragraphs (c)(10)(i)(A) through (F)
of this section is satisfied then the
proper shipping name selection process
in (c)(12)(ii) must be used.
(iii) A mixture or solution meeting
the definition of one or more hazard
class that is not identified in the Table
specifically by name, comprised of two
or more hazardous materials in the
same hazard class, must be described
using an appropriate shipping descrip-
tion (e.g., ‘‘Flammable liquid, n.o.s.’’).
The name that most appropriately de-
scribes the material shall be used; e.g.,
an alcohol not listed by its technical
name in the Table shall be described as
‘‘Alcohol, n.o.s.’’ rather than ‘‘Flam-
mable liquid, n.o.s.’’. Some mixtures
may be more appropriately described
according to their application, such as
‘‘Coating solution’’ or ‘‘Extracts, fla-
voring liquid’’ rather than by an n.o.s.
entry. Under the provisions of subparts
C and D of this part, the technical
names of at least two components most
predominately contributing to the haz-
ards of the mixture or solution may be
required in association with the proper
shipping name.
(11) Except for a material subject to
or prohibited by § 173.21, § 173.54,
§ 173.56(d), § 173.56(e), § 173.224(c) or
§ 173.225(b) of this subchapter, a mate-
rial that is considered to be a haz-
ardous waste or a sample of a material
for which the hazard class is uncertain
and must be determined by testing
may be assigned a tentative proper
shipping name, hazard class, identifica-
tion number and packing group, if ap-
plicable, based on the shipper’s ten-
tative determination according to:
(i) Defining criteria in this sub-
chapter;
(ii) The hazard precedence prescribed
in § 173.2a of this subchapter;
(iii) The shipper’s knowledge of the
material;
(iv) In addition to paragraphs
(c)(11)(i) through (iii) of this section,
for a sample of a material other than a
waste, the following must be met:
(A) Except when the word ‘‘Sample’’
already appears in the proper shipping
name, the word ‘‘Sample’’ must appear
as part of the proper shipping name or
in association with the basic descrip-
tion on the shipping paper.
(B) When the proper shipping descrip-
tion for a sample is assigned a ‘‘G’’ in
Column (1) of the § 172.101 Table, and
the primary constituent(s) for which
the tentative classification is based are
not known, the provisions requiring a
technical name for the constituent(s)
do not apply; and
(C) A sample must be transported in
a combination packaging that con-
forms to the requirements of this sub-
chapter that are applicable to the ten-
tative packing group assigned, and
may not exceed a net mass of 2.5 kg (5.5
pounds) per package.
N
OTE TO PARAGRAPH
(c)(11): For the trans-
portation of samples of self-reactive mate-
rials, organic peroxides, explosives or light-
ers,
see
§ 173.224(c)(3), § 173.225(c)(2), § 173.56(d)
or § 173.308(b)(2) of this subchapter, respec-
tively.
(12) Except when the proper shipping
name in the Table is preceded by a plus
(+)—
(i) If it is specifically determined
that a material meets the definition of
a hazard class, packing group or hazard
zone, other than the class, packing
group or hazard zone shown in associa-
tion with the proper shipping name, or
does not meet the defining criteria for
a subsidiary hazard shown in Column 6
of the Table, the material shall be de-
scribed by an appropriate proper ship-
ping name listed in association with
the correct hazard class, packing
156
49 CFR Ch. I (10–1–23 Edition)
§ 172.101
group, hazard zone, or subsidiary haz-
ard for the material.
(ii)
Generic or n.o.s. descriptions.
If an
appropriate technical name is not
shown in the Table, selection of a prop-
er shipping name shall be made from
the generic or n.o.s. descriptions cor-
responding to the specific hazard class,
packing group, hazard zone, or sub-
sidiary hazard, if any, for the material.
The name that most appropriately de-
scribes the material shall be used; e.g.,
an alcohol not listed by its technical
name in the Table shall be described as
‘‘Alcohol, n.o.s.’’ rather than ‘‘Flam-
mable liquid, n.o.s.’’. Some mixtures
may be more appropriately described
according to their application, such as
‘‘Coating solution’’ or ‘‘Extracts, fla-
voring, liquid’’, rather than by an n.o.s.
entry, such as ‘‘Flammable liquid,
n.o.s.’’ It should be noted, however,
that an n.o.s. description as a proper
shipping name may not provide suffi-
cient information for shipping papers
and package markings. Under the pro-
visions of subparts C and D of this part,
the technical name of one or more con-
stituents which makes the product a
hazardous material may be required in
association with the proper shipping
name.
(iii)
Multiple hazard materials.
If a ma-
terial meets the definition of more
than one hazard class, and is not iden-
tified in the Table specifically by name
(e.g., acetyl chloride), the hazard class
of the material shall be determined by
using the precedence specified in
§ 173.2a of this subchapter, and an ap-
propriate shipping description (e.g.,
‘‘Flammable liquid, corrosive n.o.s.’’)
shall be selected as described in para-
graph (c)(12)(ii) of this section.
(iv) If it is specifically determined
that a material is not a forbidden ma-
terial and does not meet the definition
of any hazard class, the material is not
a hazardous material.
(13)
Self-reactive materials and organic
peroxides.
A generic proper shipping
name for a self-reactive material or an
organic peroxide, as listed in Column 2
of the Table, must be selected based on
the material’s technical name and con-
centration, in accordance with the pro-
visions of § 173.224 or § 173.225 of this
subchapter, respectively.
(14) A proper shipping name that de-
scribes all isomers of a material may
be used to identify any isomer of that
material if the isomer meets criteria
for the same hazard class or division,
subsidiary risk(s) and packing group,
unless the isomer is specifically identi-
fied in the Table.
(15) Unless a hydrate is specifically
listed in the Table, a proper shipping
name for the equivalent anhydrous
substance may be used, if the hydrate
meets the same hazard class or divi-
sion, subsidiary risk(s) and packing
group.
(16) Unless it is already included in
the proper shipping name in the
§ 172.101 Table, the qualifying words
‘‘liquid’’ or ‘‘solid’’ may be added in as-
sociation with the proper shipping
name when a hazardous material spe-
cifically listed by name in the § 172.101
Table may, due to the differing phys-
ical states of the various isomers of the
material, be either a liquid or a solid
(for example ‘‘Dinitrotoluenes, liquid’’
and ‘‘Dinitrotoluenes, solid’’). Use of
the words ‘‘liquid’’ or ‘‘solid’’ is subject
to the limitations specified for the use
of the words ‘‘mixture’’ or ‘‘solution’’
in paragraph (c)(10) of this section. The
qualifying word ‘‘molten’’ may be
added in association with the proper
shipping name when a hazardous mate-
rial, which is a solid in accordance
with the definition in § 171.8 of this sub-
chapter, is offered for transportation in
the molten state (for example,
‘‘Alkylphenols, solid, n.o.s., molten’’).
(17) Unless it is already included in
the proper shipping name in the
§ 172.101 Table, the qualifying word
‘‘stabilized’’ may be added in associa-
tion with the proper shipping name, as
appropriate, where without stabiliza-
tion the substance would be forbidden
for transportation according to
§ 173.21(f) of this subchapter.
(d)
Column 3: Hazard class or Division.
Column 3 contains a designation of the
hazard class or division corresponding
to each proper shipping name, or the
word ‘‘Forbidden’’.
(1) A material for which the entry in
this column is ‘‘Forbidden’’ may not be
offered for transportation or trans-
ported. This prohibition does not apply
if the material is diluted, stabilized or
incorporated in a device and it is
157
Pipeline and Haz. Matls. Safety Admin., DOT
§ 172.101
classed in accordance with the defini-
tions of hazardous materials contained
in part 173 of this subchapter.
(2) When a reevaluation of test data
or new data indicates a need to modify
the ‘‘Forbidden’’ designation or the
hazard class or packing group specified
for a material specifically identified in
the Table, this data should be sub-
mitted to the Associate Administrator.
(3) A basic description of each hazard
class and the section reference for class
definitions appear in § 173.2 of this sub-
chapter.
(4) Each reference to a Class 3 mate-
rial is modified to read ‘‘Combustible
liquid’’ when that material is reclassi-
fied in accordance with § 173.150(e) or (f)
of this subchapter or has a flash point
above 60
°
C (140
°
F) but below 93
°
C (200
°
F).
(e)
Column 4: Identification number.
Column 4 lists the identification num-
ber assigned to each proper shipping
name. Those preceded by the letters
‘‘UN’’ are associated with proper ship-
ping names considered appropriate for
international transportation as well as
domestic transportation. Those pre-
ceded by the letters ‘‘NA’’ are associ-
ated with proper shipping names not
recognized for transportation outside
of the United States. Identification
numbers in the ‘‘NA9000’’ series are as-
sociated with proper shipping names
not appropriately covered by inter-
national hazardous materials (dan-
gerous goods) transportation stand-
ards, or not appropriately addressed by
international transportation standards
for emergency response information
purposes, except for transportation in
the United States. Those preceded by
the letters ‘‘ID’’ are associated with
proper shipping names recognized by
the ICAO Technical Instructions (see
§ 171.7 of this subchapter for avail-
ability).
(f)
Column 5: Packing group.
Column 5
specifies one or more packing groups
assigned to a material corresponding to
the proper shipping name and hazard
class for that material. Class 2, Class 7,
and Division 6.2 do not have packing
groups. Articles in classes other than
Class 1 are not assigned to packing
groups. For packing purposes, any re-
quirement for a specific packaging per-
formance level is set out in the appli-
cable packing authorizations of part
173. Packing Groups I, II, and III indi-
cate the degree of danger presented by
the material is great, medium, or
minor, respectively. If more than one
packing group is indicated for an
entry, the packing group for the haz-
ardous material is determined using
the criteria for assignment of packing
groups specified in subpart D of part
173. When a reevaluation of test data or
new data indicates a need to modify
the specified packing group(s), the data
should be submitted to the Associate
Administrator. Each reference in this
column to a material that is a haz-
ardous waste or a hazardous substance,
and whose proper shipping name pre-
ceded in Column 1 of the Table by the
letter ‘‘A’’ or ‘‘W,’’ is modified to read
‘‘III’’ on those occasions when the ma-
terial is offered for transportation or
transported by a mode in which its
transportation is not otherwise subject
to requirements of this subchapter.
(g)
Column 6: Labels.
Column 6 speci-
fies codes which represent the hazard
warning labels required for a package
filled with a material conforming to
the associated hazard class and proper
shipping name, unless the package is
otherwise excepted from labeling by a
provision in subpart E of this part, or
part 173 of this subchapter. The first
code is indicative of the primary haz-
ard of the material. Additional label
codes are indicative of subsidiary haz-
ards. Provisions in § 172.402 may require
that a label other than that specified
in Column 6 be affixed to the package
in addition to that specified in Column
6. No label is required for a material
classed as a combustible liquid or for a
Class 3 material that is reclassed as a
combustible liquid. For ‘‘Empty’’ label
requirements, see § 173.428 of this sub-
chapter. The codes contained in Col-
umn 6 are defined according to the fol-
lowing table:
L
ABEL
S
UBSTITUTION
T
ABLE
Label code
Label name
1 ................................................
Explosive
1.1
1
...........................................
Explosive 1.1
1
1.2
1
...........................................
Explosive 1.2
1
1.3
1
...........................................
Explosive 1.3
1
1.4
1
...........................................
Explosive 1.4
1
1.5
1
...........................................
Explosive 1.5
1
1.6
1
...........................................
Explosive 1.6
1
2.1 .............................................
Flammable Gas
158
49 CFR Ch. I (10–1–23 Edition)
§ 172.101
L
ABEL
S
UBSTITUTION
T
ABLE
—Continued
Label code
Label name
2.2 .............................................
Non-Flammable Gas
2.3 .............................................
Poison Gas
3 ................................................
Flammable Liquid
4.1 .............................................
Flammable Solid
4.2 .............................................
Spontaneously Combustible
4.3 .............................................
Dangerous When Wet
5.1 .............................................
Oxidizer
5.2 .............................................
Organic Peroxide
6.1 (inhalation hazard, Zone A
or B).
Poison Inhalation Hazard
6.1 (other than inhalation haz-
ard, Zone A or B)
2
.
Poison
6.2 .............................................
Infectious substance
7 ................................................
Radioactive
8 ................................................
Corrosive
9 ................................................
Class 9
1
Refers to the appropriate compatibility group letter.
2
The packing group for a material is indicated in column 5
of the table.
(h)
Column 7: Special provisions.
Col-
umn 7 specifies codes for special provi-
sions applicable to hazardous mate-
rials. When Column 7 refers to a special
provision for a hazardous material, the
meaning and requirements of that spe-
cial provision are as set forth in
§ 172.102 of this subpart.
(i)
Column 8: Packaging authorizations.
Columns 8A, 8B and 8C specify the ap-
plicable sections for exceptions, non-
bulk packaging requirements and bulk
packaging requirements, respectively,
in part 173 of this subchapter. Columns
8A, 8B and 8C are completed in a man-
ner which indicates that ‘‘§ 173.’’ pre-
cedes the designated numerical entry.
For example, the entry ‘‘202’’ in Col-
umn 8B associated with the proper
shipping name ‘‘Gasoline’’ indicates
that for this material conformance to
non-bulk packaging requirements pre-
scribed in § 173.202 of this subchapter is
required. When packaging require-
ments are specified, they are in addi-
tion to the standard requirements for
all packagings prescribed in § 173.24 of
this subchapter and any other applica-
ble requirements in subparts A and B
of part 173 of this subchapter.
(1) Exceptions. Column 8A contains
exceptions from some of the require-
ments of this subchapter. The ref-
erenced exceptions are in addition to
those specified in subpart A of part 173
and elsewhere in this subchapter. A
‘‘None’’ in this column means no pack-
aging exceptions are authorized, except
as may be provided by special provi-
sions in Column 7.
(2) Non-bulk packaging. Column 8B
references the section in part 173 of
this subchapter which prescribes pack-
aging requirements for non-bulk pack-
agings. A ‘‘None’’ in this column means
non-bulk packagings are not author-
ized, except as may be provided by spe-
cial provisions in Column 7. Each ref-
erence in this column to a material
which is a hazardous waste or a haz-
ardous substance, and whose proper
shipping name is preceded in Column 1
of the Table by the letter ‘‘A’’ or ‘‘W’’,
is modified to include ‘‘§ 173.203’’ or
‘‘§ 173.213’’, as appropriate for liquids
and solids, respectively, on those occa-
sions when the material is offered for
transportation or transported by a
mode in which its transportation is not
otherwise subject to the requirements
of this subchapter.
(3)
Bulk packaging.
Column (8C) speci-
fies the section in part 173 of this sub-
chapter that prescribes packaging re-
quirements for bulk packagings, sub-
ject to the limitations, requirements,
and additional authorizations of Col-
umns (7) and (8B). A ‘‘None’’ in Column
(8C) means bulk packagings are not au-
thorized, except as may be provided by
special provisions in Column (7) and in
packaging authorizations Column (8B).
Additional authorizations and limita-
tions for use of UN portable tanks are
set forth in Column 7. For each ref-
erence in this column to a material
that is a hazardous waste or a haz-
ardous substance, and whose proper
shipping name is preceded in Column 1
of the Table by the letter ‘‘A’’ or ‘‘W’’
and that is offered for transportation
or transported by a mode in which its
transportation is not otherwise subject
to the requirements of this subchapter:
(i) The column reference is § 173.240 or
§ 173.241, as appropriate.
(ii) For a solid material, the excep-
tion provided in special provision B54 is
applicable.
(iii) For a Class 9 material, which
meets the definition of an elevated
temperature material, the column ref-
erence is § 173.247.
(4) For a hazardous material which is
specifically named in the Table and
whose packaging sections specify pack-
agings not applicable to the form of the
material (e.g., packaging specified is
for solid material and the material is
159
Pipeline and Haz. Matls. Safety Admin., DOT
§ 172.101
being offered for transportation in a
liquid form) the following table should
be used to determine the appropriate
packaging section:
Packaging section reference for
solid materials
Corresponding pack-
aging section for liquid
materials
§ 173.187 .......................................
§ 173.181
§ 173.211 .......................................
§ 173.201
§ 173.212 .......................................
§ 173.202
§ 173.213 .......................................
§ 173.203
§ 173.240 .......................................
§ 173.241
§ 173.242 .......................................
§ 173.243
(5)
Cylinders.
For cylinders, both non-
bulk and bulk packaging authoriza-
tions are set forth in Column (8B). Not-
withstanding a designation of ‘‘None’’
in Column (8C), a bulk cylinder may be
used when specified through the sec-
tion reference in Column (8B).
(j)
Column 9: Quantity limitations.
Col-
umns 9A and 9B specify the maximum
quantities that may be offered for
transportation in one package by pas-
senger-carrying aircraft or passenger-
carrying rail car (Column 9A) or by
cargo aircraft only (Column 9B), sub-
ject to the following:
(1) ‘‘Forbidden’’ means the material
may not be offered for transportation
or transported in the applicable mode
of transport.
(2) The quantity limitation is ‘‘net’’
except where otherwise specified, such
as for ‘‘Consumer commodity’’ which
specifies ‘‘30 kg gross.’’
(3) When articles or devices are spe-
cifically listed by name, the net quan-
tity limitation applies to the entire ar-
ticle or device (less packaging and
packaging materials) rather than only
to its hazardous components.
(4) A package offered or intended for
transportation by aircraft and which is
filled with a material forbidden on pas-
senger-carrying aircraft but permitted
on cargo aircraft only, or which ex-
ceeds the maximum net quantity au-
thorized on passenger-carrying air-
craft, shall be labelled with the CARGO
AIRCRAFT ONLY label specified in
§ 172.448 of this part.
(5) The total net quantity of haz-
ardous material for an outer non-bulk
packaging that contains more than one
hazardous material may not exceed the
lowest permitted maximum net quan-
tity per package as shown in Column
9A or 9B, as appropriate. If one mate-
rial is a liquid and one is a solid, the
maximum net quantity must be cal-
culated in kilograms.
See
§ 173.24a(c)(1)(iv).
(k)
Column 10: Vessel stowage require-
ments.
Column 10A [Vessel stowage]
specifies the authorized stowage loca-
tions on board cargo and passenger ves-
sels. Column 10B [Other provisions]
specifies codes for stowage and han-
dling requirements for specific haz-
ardous materials. Hazardous materials
offered for transportation as limited
quantities are allocated stowage cat-
egory A and are not subject to the
stowage codes assigned by column 10B.
The meaning of each code in Column
10B is set forth in § 176.84 of this sub-
chapter. Section 176.63 of this sub-
chapter sets forth the physical require-
ments for each of the authorized loca-
tions listed in Column 10A. (For bulk
transportation by vessel, see 46 CFR
parts 30 to 40, 70, 98, 148, 151, 153 and
154.) The authorized stowage locations
specified in Column 10A are defined as
follows:
(1) Stowage category ‘‘A’’ means the
material may be stowed ‘‘on deck’’ or
‘‘under deck’’ on a cargo vessel or on a
passenger vessel.
(2) Stowage category ‘‘B’’ means—
(i) The material may be stowed ‘‘on
deck’’ or ‘‘under deck’’ on a cargo ves-
sel and on a passenger vessel carrying
a number of passengers limited to not
more than the larger of 25 passengers,
or one passenger per each 3 m of over-
all vessel length; and
(ii) ‘‘On deck only’’ on passenger ves-
sels in which the number of passengers
specified in paragraph (k)(2)(i) of this
section is exceeded.
(3) Stowage category ‘‘C’’ means the
material must be stowed ‘‘on deck
only’’ on a cargo vessel or on a pas-
senger vessel.
(4) Stowage category ‘‘D’’ means the
material must be stowed ‘‘on deck
only’’ on a cargo vessel or on a pas-
senger vessel carrying a number of pas-
sengers limited to not more than the
larger of 25 passengers or one passenger
per each 3 m of overall vessel length,
but the material is prohibited on a pas-
senger vessel in which the limiting
number of passengers is exceeded.
(5) Stowage category ‘‘E’’ means the
material may be stowed ‘‘on deck’’ or
160
49 CFR Ch. I (10–1–23 Edition)
§ 172.101
‘‘under deck’’ on a cargo vessel or on a
passenger vessel carrying a number of
passengers limited to not more than
the larger of 25 passengers, or one pas-
senger per each 3 m of overall vessel
length, but is prohibited from carriage
on a passenger vessel in which the lim-
iting number of passengers is exceeded.
(6) Stowage category ‘‘01’’ means the
material may be stowed ‘‘on deck’’ in
closed cargo transport units or ‘‘under
deck’’ on a cargo vessel (up to 12 pas-
sengers) or on a passenger vessel.
(7) Stowage category ‘‘02’’ means the
material may be stowed ‘‘on deck’’ in
closed cargo transport units or ‘‘under
deck’’ on a cargo vessel (up to 12 pas-
sengers) or ‘‘on deck’’ in closed cargo
transport units or ‘‘under deck’’ in
closed cargo transport units on a pas-
senger vessel.
(8) Stowage category ‘‘03’’ means the
material may be stowed ‘‘on deck’’ in
closed cargo transport units or ‘‘under
deck’’ on a cargo vessel (up to 12 pas-
sengers) but the material is prohibited
on a passenger vessel.
(9) Stowage category ‘‘04’’ means the
material may be stowed ‘‘on deck’’ in
closed cargo transport units or ‘‘under
deck’’ in closed cargo transports on a
cargo vessel (up to 12 passengers) but
the material is prohibited on a pas-
senger vessel.
(10) Stowage category ‘‘05’’ means the
material may be stowed ‘‘on deck’’ in
closed cargo transport units on a cargo
vessel (up to 12 passengers) but the ma-
terial is prohibited on a passenger ves-
sel.
(l)
Changes to the Table.
(1) Unless
specifically stated otherwise in a rule
document published in the F
EDERAL
R
EGISTER
amending the Table—
(i) Such a change does not apply to
the shipment of any package filled
prior to the effective date of the
amendment; and
(ii) Stocks of preprinted shipping pa-
pers and package markings may be
continued in use, in the manner pre-
viously authorized, until depleted or
for a one-year period, subsequent to
the effective date of the amendment,
whichever is less.
(2) Except as otherwise provided in
this section, any alteration of a ship-
ping description or associated entry
which is listed in the § 172.101 Table
must receive prior written approval
from the Associate Administrator.
(3) The proper shipping name of a
hazardous material changed in the May
6, 1997 final rule, in effect on October 1,
1997, only by the addition or omission
of the word ‘‘compressed,’’ ‘‘inhibited,’’
‘‘liquefied’’ or ‘‘solution’’ may continue
to be used to comply with package
marking requirements, until January
1, 2003.
161
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Accellerene, see p-
Nitrosodimethylaniline
Accumulators, electric, see Bat-
teries, wet etc
Accumulators, pressurized, pneu-
matic or hydraulic (containing
non-flamable gas), see Articles
pressurized, pneumatic or hy-
draulic (containing non-flamable
gas)
Acetal
3 UN1088
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
E
Acetaldehyde
3 UN1089
I
3
B16, T11, TP2, TP7 None
201
243
Forbidden
30 L
E
A
Acetaldehyde ammonia
9 UN1841
III
9
IB8, IP3, IP7, T1, TP33 155
204
240
200 kg
200 kg
A
34
Acetaldehyde oxime
3 UN2332
III
3
B1, IB3, T4, TP1 150
203
242
60 L
220 L
A
Acetic acid, glacial or Acetic acid
solution, with more than 80 per-
cent acid, by mass
8 UN2789
II
8, 3
A3, A7, A10, B2, IB2,
T7, TP2
154
202
243
1 L
30 L
A
53, 58
Acetic acid solution, not less than
50 percent but not more than 80
percent acid, by mass
8 UN2790
II
8
148, A3, A7, A10, B2,
IB2, T7, TP2
154
202
242
1 L
30 L
A
53, 58
Acetic acid solution, with more than
10 percent and less than 50 per-
cent acid, by mass
8 UN2790
III
8
148, IB3, T4, TP1 154
203
242
5 L
60 L
A
53, 58
Acetic anhydride
8 UN1715
II
8, 3
A3, A7, A10, B2, IB2,
T7, TP2
154
202
243
1 L
30 L
A
40, 53,
58
Acetone
3 UN1090
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
Acetone cyanohydrin, stabilized
6.1 UN1541
I
6.1
2, B9, B14, B32, B76,
B77, N34, T20, TP2,
TP13, TP38, TP45
None
227
244
Forbidden
Forbidden
D
25, 40,
52, 53
Acetone oils
3 UN1091
II
3
IB2, T4, TP1, TP8 150
202
242
5 L
60 L
B
Acetonitrile
3 UN1648
II
3
IB2, T7, TP2 150
202
242
5 L
60 L
B
40
Acetyl acetone peroxide with more
than 9 percent by mass active
oxygen
Forbidden
Acetyl benzoyl peroxide, solid, or
with more than 40 percent in so-
lution
Forbidden
162
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Acetyl bromide
8 UN1716
II
8
B2, IB2, T8, TP2 154
202
242
1 L
30 L
C
40, 53,
58
Acetyl chloride
3 UN1717
II
3, 8
A3, A7, IB1, N34, T8,
TP2
150
202
243
1 L
5 L
B
40, 53,
58
Acetyl cyclohexanesulfonyl per-
oxide, with more than 82 percent
wetted with less than 12 percent
water
Forbidden
Acetyl iodide
8 UN1898
II
8
B2, IB2, T7, TP2, TP13 154
202
242
1 L
30 L
C
40, 53,
58
Acetyl methyl carbinol
3 UN2621
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Acetyl peroxide, solid, or with more
than 25 percent in solution
Forbidden
Acetylene, dissolved
2.1 UN1001
2.1
N86, N88 None
303
None
Forbidden
15 kg
D
25, 40,
57
Acetylene (liquefied)
Forbidden
Acetylene silver nitrate
Forbidden
Acetylene, solvent free
Forbidden
Acetylene tetrabromide, see
Tetrabromoethane
Acid butyl phosphate, see Butyl
acid phosphate
Acid, sludge, see Sludge acid
Acridine
6.1 UN2713
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Acrolein dimer, stabilized
3 UN2607
III
3
387, B1, IB3, T2, TP1 150
203
242
60 L
220 L
C
25, 40
Acrolein, stabilized
6.1 UN1092
I
6.1, 3
1, 380, 387, B9, B14,
B30, B42, B77, T22,
TP2, TP7, TP13, TP38,
TP44
None
226
244
Forbidden
Forbidden
D
25, 40
Acrylamide, solid
6.1 UN2074
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
12, 25
Acrylamide solution
6.1 UN3426
III
6.1
IB3, T4, TP1 153
203
241
60 L
220 L
A
12, 25
Acrylic acid, stabilized
8 UN2218
II
8, 3
387, B2, IB2, T7, TP2 154
202
243
1 L
30 L
C
25, 40,
53, 58
Acrylonitrile, stabilized
3 UN1093
I
3, 6.1
387, B9, T14, TP2,
TP13
None
201
243
Forbidden
30 L
D
25, 40
Actuating cartridge, explosive, see
Cartridges, power device
163
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Adhesives, containing a flammable
liquid
3 UN1133
I
3
T11, TP1, TP8, TP27 150
201
243
1 L
30 L
B
II
3
149, B52, IB2, T4, TP1,
TP8
150
173
242
5 L
60 L
B
III
3
B1, B52, IB3, T2, TP1 150
173
242
60 L
220 L
A
Adiponitrile
6.1 UN2205
III
6.1
IB3, T3, TP1 153
203
241
60 L
220 L
A
G
Adsorbed gas, n.o.s
2.2 UN3511
......
2.2
........................................
None
302c
None
75 kg
150 kg
A
G
Adsorbed gas, flammable, n.o.s
2.1 UN3510
......
2.1
........................................
None
302c
None
Forbidden
150 kg
D
40
G
Adsorbed gas, oxidizing, n.o.s
2.2 UN3513
......
2.2,
5.1
........................................
None
302c
None
75 kg
150 kg
D
G
Adsorbed gas, toxic, n.o.s. Inhala-
tion hazard zone A
2.3 UN3512
......
2.3
1 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, n.o.s. Inhala-
tion hazard zone B
2.3 UN3512
......
2.3
2, B9, B14 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, n.o.s. Inhala-
tion hazard zone C
2.3 UN3512
......
2.3
3, B14 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, n.o.s. Inhala-
tion hazard zone D
2.3 UN3512
......
2.3
4 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, corrosive,
n.o.s. Inhalation hazard zone A
2.3 UN3516
......
2.3, 8
1, 379 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, corrosive,
n.o.s. Inhalation hazard zone B
2.3 UN3516
......
2.3, 8
2, 379, B9, B14 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, corrosive,
n.o.s. Inhalation hazard zone C
2.3 UN3516
......
2.3, 8
3, 379, B14 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, corrosive,
n.o.s. Inhalation hazard zone D
2.3 UN3516
......
2.3, 8
4, 379 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, flammable,
n.o.s. Inhalation hazard zone A
2.3 UN3514
......
2.3,
2.1
1 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, flammable,
n.o.s. Inhalation hazard zone B
2.3 UN3514
......
2.3,
2.1
2, B9, B14 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, flammable,
n.o.s. Inhalation hazard zone C
2.3 UN3514
......
2.3,
2.1
3, B14 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, flammable,
n.o.s. Inhalation hazard zone D
2.3 UN3514
......
2.3,
2.1
4 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, flammable,
corrosive, n.o.s. Inhalation hazard
zone A
2.3 UN3517
......
2.3,
2.1,
8
1 None
302c
None
Forbidden
Forbidden
D
17, 40
G
Adsorbed gas, toxic, flammable,
corrosive, n.o.s. Inhalation hazard
zone B
2.3 UN3517
......
2.3,
2.1,
8
2, B9, B14 None
302c
None
Forbidden
Forbidden
D
17, 40
G
Adsorbed gas, toxic, flammable,
corrosive, n.o.s. Inhalation hazard
zone C
2.3 UN3517
......
2.3,
2.1,
8
3, B14 None
302c
None
Forbidden
Forbidden
D
17, 40
G
Adsorbed gas, toxic, flammable,
corrosive, n.o.s. Inhalation hazard
zone D
2.3 UN3517
......
2.3,
2.1,
8
4 None
302c
None
Forbidden
Forbidden
D
17, 40
G
Adsorbed gas, toxic, oxidizing,
n.o.s. Inhalation hazard zone A
2.3 UN3515
......
2.3,
5.1
1 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, oxidizing,
n.o.s. Inhalation hazard zone B
2.3 UN3515
......
2.3,
5.1
2, B9, B14 None
302c
None
Forbidden
Forbidden
D
40
164
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
G
Adsorbed gas, toxic, oxidizing,
n.o.s. Inhalation hazard zone C
2.3 UN3515
......
2.3,
5.1
3, B14 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, oxidizing,
n.o.s. Inhalation hazard zone D
2.3 UN3515
......
2.3,
5.1
4 None
302c
None
Forbidden
Forbidden
D
40
G
Adsorbed gas, toxic, oxidizing, cor-
rosive, n.o.s. Inhalation hazard
zone A
2.3 UN3518
......
2.3,
5.1,
8
1 None
302c
None
Forbidden
Forbidden
D
40, 89,
90
G
Adsorbed gas, toxic, oxidizing, cor-
rosive, n.o.s. Inhalation hazard
zone B
2.3 UN3518
......
2.3,
5.1,
8
2, B9, B14 None
302c
None
Forbidden
Forbidden
D
40, 89,
90
G
Adsorbed gas, toxic, oxidizing, cor-
rosive, n.o.s. Inhalation hazard
zone C
2.3 UN3518
......
2.3,
5.1,
8
3, B14 None
302c
None
Forbidden
Forbidden
D
40, 89,
90
G
Adsorbed gas, toxic, oxidizing, cor-
rosive, n.o.s. Inhalation hazard
zone D
2.3 UN3518
......
2.3,
5.1,
8
4 None
302c
None
Forbidden
Forbidden
D
40, 89,
90
Aerosols, corrosive, Packing Group
II or III, (each not exceeding 1 L
capacity)
2.2 UN1950
......
2.2, 8
A34 306
None
None
75 kg
150 kg
A
25, 87,
126,
157
Aerosols, flammable, (each not ex-
ceeding 1 L capacity)
2.1 UN1950
......
2.1
N82 306
None
None
75 kg
150 kg
A
25, 87,
126,
157
Aerosols, flammable, n.o.s. (engine
starting fluid) (each not exceeding
1 L capacity)
2.1 UN1950
......
2.1
N82 306
304
None
Forbidden
150 kg
A
25, 87,
126,
157
Aerosols, non-flammable, (each not
exceeding 1 L capacity)
2.2 UN1950
......
2.2
........................................
306
None
None
75 kg
150 kg
A
25, 87,
126,
157
Aerosols, poison, Packing Group III
(each not exceeding 1 L capacity)
2.2 UN1950
......
2.2,
6.1
........................................
306
None
None
Forbidden
Forbidden
A
25, 87,
126,
157
Air bag inflators, or Air bag mod-
ules, or Seat-belt pretensioners,
see Safety devices, electrically
initiated or Safety devices, pyro-
technic
165
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Air, compressed
2.2 UN1002
2.2
78 306,
307
302
302
75 kg
150 kg
A
Air, refrigerated liquid, (cryogenic
liquid)
2.2 UN1003
2.2,
5.1
T75, TP5, TP22 320
316
318,
319
Forbidden
Forbidden
D
51
Air, refrigerated liquid, (cryogenic
liquid) non-pressurized
2.2 UN1003
2.2,
5.1
T75, TP5, TP22 320
316
318,
319
Forbidden
Forbidden
D
51
Aircraft engines (including turbines),
see Engines, internal combustion
Aircraft evacuation slides, see Life
saving appliances etc
Aircraft hydraulic power unit fuel
tank (containing a mixture of an-
hydrous hydrazine and
monomethyl hydrazine) (M86
fuel)
3 UN3165
I
3, 6.1,
8
........................................
None
172
None
Forbidden
42 L
E
21, 40,
49, 100
Aircraft survival kits, see Life saving
appliances etc
G
Alcoholates solution, n.o.s., in alco-
hol
3 UN3274
II
3, 8
IB2 150
202
243
1 L
5 L
B
52
Alcoholic beverages
3 UN3065
II
3
24, 149, B1, IB2, T4,
TP1
150
202
242
5 L
60 L
A
III
3
24, B1, IB3, N11, T2,
TP1
150
203
242
60 L
220 L
A
Alcohols, n.o.s.
3 UN1987
I
3
172, T11, TP1, TP8,
TP27
4b
201
243
1 L
30 L
E
II
3
172, IB2, T7, TP1, TP8,
TP28
4b, 150
202
242
5 L
60 L
B
III
3
172, B1, IB3, T4, TP1,
TP29
4b, 150
203
242
60 L
220 L
A
G
Alcohols, flammable, toxic n.o.s
3 UN1986
I
3, 6.1
T14, TP2, TP13, TP27 None
201
243
Forbidden
30 L
E
40
II
3, 6.1
IB2, T11, TP2, TP27 150
202
243
1 L
60 L
B
40
III
3, 6.1
B1, IB3, T7, TP1, TP28 150
203
242
60 L
220 L
A
Aldehydes, n.o.s.
3 UN1989
I
3
T11, TP1, TP27 None
201
243
1 L
30 L
E
II
3
IB2, T7, TP1, TP8, TP28 150
202
242
5 L
60 L
B
III
3
B1, IB3, T4, TP1, TP29 150
203
242
60 L
220 L
A
G
Aldehydes, flammable, toxic, n.o.s.
3 UN1988
I
3, 6.1
T14, TP2, TP13, TP27 None
201
243
Forbidden
30 L
E
40
II
3, 6.1
IB2, T11, TP2, TP27 150
202
243
1 L
60 L
B
40
III
3, 6.1
B1, IB3, T7, TP1, TP28 150
203
242
60 L
220 L
A
Aldol
6.1 UN2839
II
6.1
IB2, T7, TP2 153
202
243
5 L
60 L
A
12, 25
G
Alkali metal alcoholates, self-heat-
ing, corrosive, n.o.s.
4.2 UN3206
II
4.2, 8
64, A7, IB5, IP2, T3,
TP33, W31
None
212
242
15 kg
50 kg
B
52
................
III
4.2, 8
64, A7, IB8, IP3, T1,
TP33, W31
None
213
242
25 kg
100 kg
B
52
Alkali metal alloys, liquid, n.o.s
4.3 UN1421
I
4.3
A2, A7, B48, N34, W31 None
201
244
Forbidden
1 L
D
13, 52,
148
Alkali metal amalgam, liquid
4.3 UN1389
I
4.3
A2, A7, N34, W31 None
201
244
Forbidden
1 L
D
13, 40,
52, 148
Alkali metal amalgam, solid
4.3 UN3401
I
4.3
IB4, IP1, N40, T9, TP7,
TP33, W31
None
211
242
Forbidden
15 kg
D
13, 52,
148
166
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Alkali metal amides
4.3 UN1390
II
4.3
A6, A7, A8, A19, A20,
IB7, IP2, IP21, T3,
TP33, W31, W40
151
212
241
15 kg
50 kg
E
13, 40,
52, 148
Alkali metal dispersions, flammable
or Alkaline earth metal disper-
sions, flammable
4.3 UN3482
I
4.3, 3
A2, A7, W31 None
201
244
Forbidden
1 L
D
13, 52,
148
Alkali metal dispersions, or Alkaline
earth metal dispersions
4.3 UN1391
I
4.3
A2, A7, W31 None
201
244
Forbidden
1 L
D
13, 52,
148
Alkaline corrosive liquids, n.o.s.,
see Caustic alkali liquids, n.o.s.
G
Alkaline earth metal alcoholates,
n.o.s
4.2 UN3205
II
4.2
65, A7, IB6, IP2, T3,
TP33, W31
None
212
241
15 kg
50 kg
B
III
4.2
65, A7, IB8, IP3, T1,
TP33, W31
None
213
241
25 kg
100 kg
B
Alkaline earth metal alloys, n.o.s
4.3 UN1393
II
4.3
A19, IB7, IP2, IP4, T3,
TP33, W31, W40
151
212
241
15 kg
50 kg
E
13, 52,
148
Alkaline earth metal amalgams, liq-
uid
4.3 UN1392
I
4.3
A19, N34, N40, W31 None
201
244
Forbidden
1 L
E
13, 40,
52, 148
Alkaline earth metal amalgams,
solid
4.3 UN3402
I
4.3
A19, N34, N40, T9, TP7,
TP33, W31
None
211
242
Forbidden
15 kg
D
13, 52,
148
G
Alkaloids, liquid, n.o.s., or Alkaloid
salts, liquid, n.o.s.
6.1 UN3140
I
6.1
A4, T14, TP2, TP27 None
201
243
1 L
30 L
A
II
6.1
IB2, T11, TP2, TP27 153
202
243
5 L
60 L
A
III
6.1
IB3, T7, TP1, TP28 153
203
241
60 L
220 L
A
G
Alkaloids, solid, n.o.s. or Alkaloid
salts, solid, n.o.s. poisonous
6.1 UN1544
I
6.1
IB7, IP1, T6, TP33 None
211
242
5 kg
50 kg
A
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Alkyl sulfonic acids, liquid or Aryl
sulfonic acids, liquid with more
than 5 percent free sulfuric acid
8 UN2584
II
8
B2, IB2, T8, TP2, TP13 154
202
242
1 L
30 L
B
53, 58
Alkyl sulfonic acids, liquid or Aryl
sulfonic acids, liquid with not
more than 5 percent free sulfuric
acid
8 UN2586
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
B
53, 58
Alkyl sulfonic acids, solid or Aryl
sulfonic acids, solid, with more
than 5 percent free sulfuric acid
8 UN2583
II
8
IB8, IP2, IP4, T3, TP33 154
212
240
15 kg
50 kg
A
53, 58
167
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Alkyl sulfonic acids, solid or Aryl
sulfonic acids, solid with not more
than 5 percent free sulfuric acid
8 UN2585
III
8
IB8, IP3, T1, TP33 154
213
240
25 kg
100 kg
A
53, 58
Alkylphenols, liquid, n.o.s. (including
C2–C12 homologues)
8 UN3145
I
8
T14, TP2 None
201
243
0.5 L
2.5 L
B
II
8
IB2, T11, TP2, TP27 154
202
242
1 L
30 L
B
III
8
IB3, T7, TP1, TP28 154
203
241
5 L
60 L
A
Alkylphenols, solid, n.o.s. (including
C2-C12 homologues)
8 UN2430
I
8
IB7, IP1, T6, TP33 None
211
242
1 kg
25 kg
B
II
8
IB8, IP2, IP4, T3, TP33 154
212
240
15 kg
50 kg
B
III
8
IB8, IP3, T1, TP33 154
213
240
25 kg
100 kg
A
Alkylsulfuric acids
8 UN2571
II
8
B2, IB2, T8, TP2, TP13,
TP28
154
202
242
1 L
30 L
C
14, 53,
58
Allethrin, see Pesticides, liquid,
toxic, n.o.s.
Allyl acetate
3 UN2333
II
3, 6.1
IB2, T7, TP1, TP13 150
202
243
1 L
60 L
E
40
Allyl alcohol
6.1 UN1098
I
6.1, 3
2, B9, B14, B32, B77,
T20, TP2, TP13, TP38,
TP45
None
227
244
Forbidden
Forbidden
D
40
Allyl bromide
3 UN1099
I
3, 6.1
T14, TP2, TP13 None
201
243
Forbidden
30 L
B
40
Allyl chloride
3 UN1100
I
3, 6.1
T14, TP2, TP13 None
201
243
Forbidden
30 L
E
40
Allyl chlorocarbonate, see Allyl
chloroformate
Allyl chloroformate
6.1 UN1722
I
6.1, 3,
8
2, B9, B14, B32, N41,
T20, TP2, TP13, TP38,
TP45
None
227
244
Forbidden
Forbidden
D
21, 40,
53, 58,
100
Allyl ethyl ether
3 UN2335
II
3, 6.1
IB2, T7, TP1, TP13 150
202
243
1 L
60 L
E
40
Allyl formate
3 UN2336
I
3, 6.1
T14, TP2, TP13 None
201
243
Forbidden
30 L
E
40
Allyl glycidyl ether
3 UN2219
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Allyl iodide
3 UN1723
II
3, 8
A3, IB1, N34, T7, TP2,
TP13
150
202
243
1 L
5 L
B
40, 53,
58
Allyl isothiocyanate, stabilized
6.1 UN1545
II
6.1, 3
387, A3, A7, IB2, T7,
TP2
153
202
243
Forbidden
60 L
D
25, 40
Allylamine
6.1 UN2334
I
6.1, 3
2, B9, B14, B32, T20,
TP2, TP13, TP38, TP45
None
227
244
Forbidden
Forbidden
D
40, 52
Allyltrichlorosilane, stabilized
8 UN1724
II
8, 3
387, A7, B2, B6, N34,
T10, TP2, TP7, TP13
None
206
243
Forbidden
30 L
C
25, 40,
53, 58
Aluminum borohydride or Aluminum
borohydride in devices
4.2 UN2870
I
4.2,
4.3
B11, T21, TP7, TP33 None
181
244
Forbidden
Forbidden
D
13, 148
Aluminum bromide, anhydrous
8 UN1725
II
8
IB8, IP2, IP4, T3, TP33 154
212
240
15 kg
50 kg
A
40, 53,
58
Aluminum bromide, solution
8 UN2580
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
53, 58
Aluminum carbide
4.3 UN1394
II
4.3
A20, IB7, IP2, IP21,
N41, T3, TP33, W31,
W40
151
212
242
15 kg
50 kg
A
13, 52,
148
Aluminum chloride, anhydrous
8 UN1726
II
8
IB8, IP2, IP4, T3, TP33 154
212
240
15 kg
50 kg
A
40, 53,
58
Aluminum chloride, solution
8 UN2581
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
53, 58
Aluminum dross, wet or hot
Forbidden
168
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Aluminum ferrosilicon powder
4.3 UN1395
II
4.3,
6.1
A19, IB5, IP2, T3, TP33,
W31, W40
151
212
242
15 kg
50 kg
A
13, 39,
40, 52,
53, 85,
103,
148
III
4.3,
6.1
A19, A20, IB4 151
213
241
25 kg
100 kg
A
13, 39,
40, 52,
53, 85,
103,
148
Aluminum hydride
4.3 UN2463
I
4.3
A19, N40, W31 None
211
242
Forbidden
15 kg
E
13, 148
D
Aluminum, molten
9 NA9260
III
9
IB3, T1, TP3 None
None
247
Forbidden
Forbidden
D
Aluminum nitrate
5.1 UN1438
III
5.1
A1, A29, IB8, IP3, T1,
TP33
152
213
240
25 kg
100 kg
A
Aluminum phosphate solution, see
Corrosive liquids, etc
Aluminum phosphide
4.3 UN1397
I
4.3,
6.1
A8, A19, N40, W31 None
211
242
Forbidden
15 kg
E
13, 40,
52, 85,
148
Aluminum phosphide pesticides
6.1 UN3048
I
6.1
A8, IB7, IP1, T6, TP33,
W31
None
211
242
Forbidden
15 kg
E
40, 85
Aluminum powder, coated
4.1 UN1309
II
4.1
IB8, IP2, IP21, T3,
TP33, W100
151
212
240
15 kg
50 kg
A
13, 39,
52, 53,
74,
101,
147,
148
III
4.1
B134, IB8, IP21, T1,
TP33, W100
151
213
240
25 kg
100 kg
A
13, 39,
52, 53,
74,
101,
147,
148
Aluminum powder, uncoated
4.3 UN1396
II
4.3
A19, A20, IB7, IP2,
IP21, T3, TP33, W31,
W40
151
212
242
15 kg
50 kg
A
13, 39,
52, 53,
148
169
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
III
4.3
A19, A20, IB8, IP21, T1,
TP33, W31
151
213
241
25 kg
100 kg
A
13, 39,
52, 53,
148
Aluminum resinate
4.1 UN2715
III
4.1
IB6, T1, TP33 151
213
240
25 kg
100 kg
A
Aluminum silicon powder, uncoated
4.3 UN1398
III
4.3
A1, A19, B136, IB8, IP4,
T1, TP33, W31
151
213
241
25 kg
100 kg
A
13, 39,
40, 52,
53, 85,
103,
148
Aluminum smelting by-products or
Aluminum remelting by-products
4.3 UN3170
II
4.3
128, B115, IB7, IP2,
IP21, T3, TP33, W31,
W40
151
212
242
15 kg
50 kg
B
13, 85,
103,
148
III
4.3
128, B115, IB8, IP21,
T1, TP33, W31
151
213
241
25 kg
100 kg
B
13, 85,
103,
148
Amatols, see Explosives, blasting,
type B
G
Amine, flammable, corrosive, n.o.s.
or Polyamines, flammable, corro-
sive, n.o.s
3 UN2733
I
3, 8
T14, TP1, TP27 None
201
243
0.5 L
2.5 L
D
40, 52
II
3, 8
IB2, T11, TP1, TP27 150
202
243
1 L
5 L
B
40, 52
III
3, 8
B1, IB3, T7, TP1, TP28 150
203
242
5 L
60 L
A
40, 52
G
Amine, liquid, corrosive, flammable,
n.o.s. or Polyamines, liquid, cor-
rosive, flammable, n.o.s.
8 UN2734
I
8, 3
A3, N34, T14, TP2,
TP27
None
201
243
0.5 L
2.5 L
A
52
II
8, 3
IB2, T11, TP2, TP27 154
202
243
1 L
30 L
A
52
G
Amines, liquid, corrosive, n.o.s. or
Polyamines, liquid, corrosive,
n.o.s
8 UN2735
I
8
B10, N34, T14, TP2,
TP27
None
201
243
0.5 L
2.5 L
A
52
II
8
B2, IB2, T11, TP1, TP27 154
202
242
1 L
30 L
A
52
III
8
IB3, T7, TP1, TP28 154
203
241
5 L
60 L
A
52
G
Amines, solid, corrosive, n.o.s., or
Polyamines, solid, corrosive
n.o.s.
8 UN3259
I
8
IB7, IP1, T6, TP33 None
211
242
1 kg
25 kg
A
52
II
8
IB8, IP2, IP4, T3, TP33 154
212
240
15 kg
50 kg
A
52
III
8
IB8, IP3, T1, TP33 154
213
240
25 kg
100 kg
A
52
2-Amino-4-chlorophenol
6.1 UN2673
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
2-Amino-5-diethylaminopentane
6.1 UN2946
III
6.1
IB3, T4, TP1 153
203
241
60 L
220 L
A
2-Amino-4,6-Dinitrophenol, wetted
with not less than 20 percent
water by mass
4.1 UN3317
I
4.1
23, A8, A19, A20, N41,
W31
None
211
None
1 kg
15 kg
E
28, 36
2-(2-Aminoethoxy) ethanol
8 UN3055
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
52
N-Aminoethylpiperazine
8 UN2815
III
8, 6.1
IB3, T4, TP1 154
203
241
5 L
60 L
B
12, 25,
40, 52
+
Aminophenols (o-; m-; p-)
6.1 UN2512
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Aminopropyldiethanolamine, see
Amines, etc
n-Aminopropylmorpholine, see
Amines, etc
170
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Aminopyridines (o-; m-; p-)
6.1 UN2671
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
B
12, 25,
40, 52
I
Ammonia, anhydrous
2.3 UN1005
......
2.3, 8
4, 379, N87, T50 None
304
314,
315
Forbidden
Forbidden
D
40, 52,
57
D
Ammonia, anhydrous
2.2 UN1005
......
2.2
13, 379, T50 None
304
314,
315
Forbidden
Forbidden
D
40, 52,
57
Ammonia solution, relative density
less than 0.880 at 15 degrees C
in water, with more than 35 per-
cent but not more than 50 per-
cent ammonia
2.2 UN2073
2.2
N87 306
304
314,
315
Forbidden
150 kg
E
40, 52,
57
Ammonia solution, relative density
between 0.880 and 0.957 at 15
degrees C in water, with more
than 10 percent but not more
than 35 percent ammonia
8 UN2672
III
8
336, IB3, IP8, T7, TP2 154
203
241
5 L
60 L
A
40, 52,
85
I
Ammonia solution, relative density
less than 0.880 at 15 degrees C
in water, with more than 50 per-
cent ammonia
2.3 UN3318
2.3, 8
4, N87, T50 None
304
314,
315
Forbidden
Forbidden
D
40, 52,
57
D
Ammonia solution, relative density
less than 0.880 at 15 degrees C
in water, with more than 50 per-
cent ammonia
2.2 UN3318
2.2
13, T50 None
304
314,
315
Forbidden
Forbidden
D
40, 52,
57
Ammonium arsenate
6.1 UN1546
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
53
Ammonium azide
Forbidden
Ammonium bifluoride, solid, see
Ammonium hydrogen difluoride,
solid
Ammonium bifluoride solution, see
Ammonium hydrogen difluoride,
solution
Ammonium bromate
Forbidden
Ammonium chlorate
Forbidden
Ammonium dichromate
5.1 UN1439
II
5.1
IB8, IP2, IP4, T3, TP33 152
212
242
5 kg
25 kg
A
52
Ammonium dinitro-o-cresolate, solid
6.1 UN1843
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
B
36, 65,
66, 77
171
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Ammonium dinitro-o-cresolate solu-
tion
6.1 UN3424
II
6.1
IB2, T7, TP2 153
202
243
5 L
60 L
B
36, 66,
78, 91
III
6.1
IB2, T7, TP2 153
203
241
60 L
220 L
A
36, 66,
78, 91
Ammonium fluoride
6.1 UN2505
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
52
Ammonium fluorosilicate
6.1 UN2854
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
52
Ammonium fulminate
Forbidden
Ammonium hydrogen sulfate
8 UN2506
II
8
IB8, IP2, IP4, T3, TP33 154
212
240
15 kg
50 kg
A
40, 53,
58
Ammonium hydrogendifluoride,
solid
8 UN1727
II
8
IB8, IP2, IP4, N34, T3,
TP33
154
212
240
15 kg
50 kg
A
25, 40,
52, 53,
58
Ammonium hydrogendifluoride, so-
lution
8 UN2817
II
8, 6.1
IB2, N34, T8, TP2, TP13 154
202
243
1 L
30 L
B
40, 53,
58
III
8, 6.1
IB3, N3, T4, TP1, TP13 154
203
241
5 L
60 L
B
40, 53,
58, 95
Ammonium hydrosulfide, solution,
see Ammonium sulfide solution
D
Ammonium hydroxide, see Ammo-
nia solutions, etc
Ammonium metavanadate
6.1 UN2859
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
44, 89,
100,
141
Ammonium nitrate based fertilizer
5.1 UN2067
III
5.1
52, 148, 150, B120, IB8,
IP3, T1, TP33
152
213
240
25 kg
100 kg
B
25, 59,
60, 66,
117,
124*
A W
Ammonium nitrate based fertilizer
9 UN2071
III
9
132, B136, IB8, IP3 155
213
240
200 kg
200 kg
A
Ammonium nitrate emulsion or Am-
monium nitrate suspension or
Ammonium nitrate gel, inter-
mediate for blasting explosives
5.1 UN3375
II
5.1
147, 148, 163, IB2, IP16 None
231
251
Forbidden
Forbidden
D
25, 59,
60, 66,
124
D
Ammonium nitrate-fuel oil mixture
containing only prilled ammonium
nitrate and fuel oil
1.5D NA0331
......
1.5D
148 None
62
None
Forbidden
Forbidden
03
25,
19E
Ammonium nitrate, liquid (hot con-
centrated solution)
5.1 UN2426
......
5.1
148, B5, T7 None
None
243
Forbidden
Forbidden
D
59, 60,
124
Ammonium nitrate, with more than
0.2 percent combustible sub-
stances, including any organic
substance calculated as carbon,
to the exclusion of any other
added substance
1.1D UN0222
......
1.1D
370 None
62
None
Forbidden
Forbidden
04
25,
19E
Ammonium nitrate, with not more
than 0.2% combustible sub-
stances, including any organic
substance calculated as carbon,
to the exclusion of any other
added substance
5.1 UN1942
III
5.1
148, A1, A29, B120,
IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
25, 59,
60, 66,
116,
124
Ammonium nitrite
Forbidden
172
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Ammonium perchlorate
1.1D UN0402
......
1.1D
107 None
62
None
Forbidden
Forbidden
04
25,
19E
Ammonium perchlorate
5.1 UN1442
II
5.1
107, A9, IB6, IP2, T3,
TP33
152
212
242
5 kg
25 kg
E
58, 69
Ammonium permanganate
Forbidden
Ammonium persulfate
5.1 UN1444
III
5.1
A1, A29, IB8, IP3, T1,
TP33
152
213
240
25 kg
100 kg
A
Ammonium picrate, dry or wetted
with less than 10 percent water,
by mass
1.1D UN0004
......
1.1D
........................................
None
62
None
Forbidden
Forbidden
04
25, 5E,
19E
Ammonium picrate, wetted with not
less than 10 percent water, by
mass
4.1 UN1310
I
4.1
23, A2, N41, W31 None
211
None
0.5 kg
0.5 kg
D
28, 36
Ammonium polysulfide, solution
8 UN2818
II
8, 6.1
IB2, T7, TP2, TP13 154
202
243
1 L
30 L
B
12, 25,
40, 52
III
8, 6.1
IB3, T4, TP1, TP13 154
203
241
5 L
60 L
B
12, 25,
40, 52
Ammonium polyvanadate
6.1 UN2861
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
44, 89,
100,
141
Ammonium silicofluoride, see Am-
monium fluorosilicate
Ammonium sulfide solution
8 UN2683
II
8, 6.1,
3
IB1, T7, TP2, TP13 154
202
243
1 L
30 L
B
12, 22,
25, 52,
100
Ammunition, blank, see Cartridges
for weapons, blank
Ammunition, illuminating with or
without burster, expelling charge
or propelling charge
1.2G UN0171
......
1.2G
........................................
62
62
Forbidden
Forbidden
03
25
Ammunition, illuminating with or
without burster, expelling charge
or propelling charge
1.3G UN0254
......
1.3G
........................................
62
62
Forbidden
Forbidden
03
25
Ammunition, illuminating with or
without burster, expelling charge
or propelling charge
1.4G UN0297
......
1.4G
........................................
62
62
Forbidden
75 kg
02
25
173
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Ammunition, incendiary liquid or
gel, with burster, expelling charge
or propelling charge
1.3J UN0247
......
1.3J
........................................
62
None
Forbidden
Forbidden
05
25,
23E
Ammunition, incendiary (water-acti-
vated contrivances) with burster,
expelling charge or propelling
charge, see Contrivances, water-
activated, etc.
Ammunition, incendiary, white phos-
phorus, with burster, expelling
charge or propelling charge
1.2H UN0243
......
1.2H
........................................
62
62
Forbidden
Forbidden
05
25,
14E,
15E,
17E
Ammunition, incendiary, white phos-
phorus, with burster, expelling
charge or propelling charge
1.3H UN0244
......
1.3H
........................................
62
62
Forbidden
Forbidden
05
25,
14E,
15E,
17E
Ammunition, incendiary with or with-
out burster, expelling charge, or
propelling charge
1.2G UN0009
......
1.2G
........................................
62
62
Forbidden
Forbidden
03
25
Ammunition, incendiary with or with-
out burster, expelling charge, or
propelling charge
1.3G UN0010
......
1.3G
........................................
62
62
Forbidden
Forbidden
03
25
Ammunition, incendiary with or with-
out burster, expelling charge or
propelling charge
1.4G UN0300
......
1.4G
........................................
62
62
Forbidden
75 kg
02
25
Ammunition, practice
1.4G UN0362
......
1.4G
........................................
62
62
Forbidden
75 kg
02
25
Ammunition, practice
1.3G UN0488
......
1.3G
........................................
62
62
Forbidden
Forbidden
03
25
Ammunition, proof
1.4G UN0363
......
1.4G
........................................
62
62
Forbidden
75 kg
02
25
Ammunition, rocket, see Warheads,
rocket etc
Ammunition, SA (small arms), see
Cartridges for weapons, etc
Ammunition, smoke (water-acti-
vated contrivances), white phos-
phorus, with burster, expelling
charge or propelling charge, see
Contrivances, water-activated,
etc. (UN 0248)
Ammunition, smoke (water-acti-
vated contrivances), without white
phosphorus or phosphides, with
burster, expelling charge or pro-
pelling charge, see Contrivances,
water-activated, etc. (UN 0249)
Ammunition smoke, white phos-
phorus with burster, expelling
charge, or propelling charge
1.2H UN0245
......
1.2H
........................................
62
62
Forbidden
Forbidden
05
25,
14E,
15E,
17E
174
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Ammunition, smoke, white phos-
phorus with burster, expelling
charge, or propelling charge
1.3H UN0246
......
1.3H
........................................
62
62
Forbidden
Forbidden
05
25,
14E,
15E,
17E
Ammunition, smoke with or without
burster, expelling charge or pro-
pelling charge
1.2G UN0015
......
1.2G
........................................
62
62
Forbidden
Forbidden
03
25,
17E
Ammunition, smoke with or without
burster, expelling charge or pro-
pelling charge
1.3G UN0016
......
1.3G
........................................
62
62
Forbidden
Forbidden
03
25,
17E
Ammunition, smoke with or without
burster, expelling charge or pro-
pelling charge
1.4G UN0303
......
1.4G
........................................
62
62
Forbidden
75 kg
02
25,
14E,
15E,
17E
Ammunition, sporting, see Car-
tridges for weapons, etc. (UN
0012; UN 0328; UN 0339)
Ammunition, tear-producing, non-
explosive, without burster or ex-
pelling charge, non-fuzed
6.1 UN2017
......
6.1, 8
........................................
None
212
None
Forbidden
50 kg
E
13, 40
Ammunition, tear-producing with
burster, expelling charge or pro-
pelling charge
1.2G UN0018
......
1.2G,
8,
6.1
........................................
62
62
Forbidden
Forbidden
03
25,
17E
Ammunition, tear-producing with
burster, expelling charge or pro-
pelling charge
1.3G UN0019
......
1.3G,
8,
6.1
........................................
62
62
Forbidden
Forbidden
03
25,
17E
Ammunition, tear-producing with
burster, expelling charge or pro-
pelling charge
1.4G UN0301
......
1.4G,
8,
6.1
........................................
62
62
Forbidden
75 kg
02
25,
14E,
15E,
17E
Ammunition, toxic, non-explosive,
without burster or expelling
charge, non-fuzed
6.1 UN2016
......
6.1
........................................
None
212
None
Forbidden
100 kg
E
13, 40
175
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Ammunition, toxic (water-activated
contrivances), with burster, expel-
ling charge or propelling charge,
see Contrivances, water-acti-
vated, etc
G
Ammunition, toxic with burster, ex-
pelling charge, or propelling
charge
1.2K UN0020
......
1.2K,
6.1
........................................
62
None
Forbidden
Forbidden
05
25,
14E,
15E,
17E
G
Ammunition, toxic with burster, ex-
pelling charge, or propelling
charge
1.3K UN0021
......
1.3K,
6.1
........................................
62
None
Forbidden
Forbidden
05
25,
14E,
15E,
17E
Amyl acetates
3 UN1104
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Amyl acid phosphate
8 UN2819
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
53, 58
Amyl butyrates
3 UN2620
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Amyl chloride
3 UN1107
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
Amyl formates
3 UN1109
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Amyl mercaptan
3 UN1111
II
3
A3, IB2, T4, TP1 150
202
242
5 L
60 L
B
95, 102
n-Amyl methyl ketone
3 UN1110
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Amyl nitrate
3 UN1112
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
40
Amyl nitrite
3 UN1113
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
E
40
Amylamines
3 UN1106
II
3, 8
IB2, T7, TP1 150
202
243
1 L
5 L
B
52
III
3, 8
B1, IB3, T4, TP1 150
203
242
5 L
60 L
A
52
Amyltrichlorosilane
8 UN1728
II
8
A7, B2, B6, N34, T10,
TP2, TP7, TP13
None
206
242
Forbidden
30 L
C
40, 53,
58
Anhydrous ammonia, see Ammo-
nia, anhydrous
Anhydrous hydrofluoric acid, see
Hydrogen fluoride, anhydrous
+
Aniline
6.1 UN1547
II
6.1
IB2, T7, TP2 153
202
243
5 L
60 L
A
40, 52
Aniline hydrochloride
6.1 UN1548
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Aniline oil, see Aniline
Anisidines
6.1 UN2431
III
6.1
IB3, T4, TP1 153
203
241
60 L
220 L
A
Anisole
3 UN2222
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Anisoyl chloride
8 UN1729
II
8
B2, B4, IB8, IP2, IP4,
T3, TP33
154
212
240
15 kg
50 kg
A
40, 53,
58
Anti-freeze, liquid, see Flammable
liquids, n.o.s.
Antimonous chloride, see Antimony
trichloride
G
Antimony compounds, inorganic,
liquid, n.o.s
6.1 UN3141
III
6.1
35, IB3, T7, TP1, TP28 153
203
241
60 L
220 L
A
G
Antimony compounds, inorganic,
solid, n.o.s
6.1 UN1549
III
6.1
35, IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Antimony lactate
6.1 UN1550
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Antimony pentachloride, liquid
8 UN1730
II
8
B2, IB2, T7, TP2 154
202
242
1 L
30 L
C
40, 53,
58
Antimony pentachloride, solutions
8 UN1731
II
8
B2, IB2, T7, TP2 154
202
242
1 L
30 L
C
40, 53,
58
176
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
C
40, 53,
58
Antimony pentafluoride
8 UN1732
II
8, 6.1
A3, A7, A10, IB2, N3,
N36, T7, TP2
154
202
243
Forbidden
30 L
D
40, 44,
53, 58,
89,
100,
141
Antimony potassium tartrate
6.1 UN1551
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Antimony powder
6.1 UN2871
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Antimony sulfide and a chlorate,
mixtures of
Forbidden
Antimony sulfide, solid, see Anti-
mony compounds, inorganic,
n.o.s.
Antimony trichloride, liquid
8 UN1733
II
8
B2, IB2 154
202
242
1 L
30 L
C
40, 53,
58
Antimony trichloride, solid
8 UN1733
II
8
IB8, IP2, IP4, T3, TP33 154
212
240
15 kg
50 kg
A
40, 53,
58
Aqua ammonia, see Ammonia solu-
tion, etc
Argon, compressed
2.2 UN1006
2.2
306,
307
302
314,
315
75 kg
150 kg
A
Argon, refrigerated liquid (cryogenic
liquid)
2.2 UN1951
2.2
T75, TP5 320
316
318
50 kg
500 kg
D
Arsenic
6.1 UN1558
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
Arsenic acid, liquid
6.1 UN1553
I
6.1
T20, TP2, TP7, TP13,
W31
None
201
243
1 L
30 L
B
46
Arsenic acid, solid
6.1 UN1554
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
Arsenic bromide
6.1 UN1555
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
12, 25,
40
Arsenic chloride, see Arsenic tri-
chloride
G
Arsenic compounds, liquid, n.o.s.
inorganic, including arsenates,
n.o.s.; arsenites, n.o.s.; arsenic
sulfides, n.o.s.; and organic com-
pounds of arsenic, n.o.s
6.1 UN1556
I
6.1
T14, TP2, TP13, TP27 None
201
243
1 L
30 L
B
40, 137
177
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
II
6.1
IB2, T11, TP2, TP13,
TP27
153
202
243
5 L
60 L
B
40, 137
III
6.1
IB3, T7, TP2, TP28 153
203
241
60 L
220 L
B
40, 137
G
Arsenic compounds, solid, n.o.s. in-
organic, including arsenates,
n.o.s.; arsenites, n.o.s.; arsenic
sulfides, n.o.s.; and organic com-
pounds of arsenic, n.o.s
6.1 UN1557
I
6.1
IB7, IP1, T6, TP33 None
211
242
5 kg
50 kg
A
137
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
137
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
137
Arsenic pentoxide
6.1 UN1559
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
Arsenic sulfide and a chlorate, mix-
tures of
Forbidden
Arsenic trichloride
6.1 UN1560
I
6.1
2, B9, B14, B32, T20,
TP2, TP13, TP38, TP45
None
227
244
Forbidden
Forbidden
B
40
Arsenic trioxide
6.1 UN1561
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
Arsenic, white, solid, see Arsenic
trioxide
Arsenical dust
6.1 UN1562
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
Arsenical pesticides, liquid, flam-
mable, toxic, flash point less than
23 degrees C
3 UN2760
I
3, 6.1
T14, TP2, TP13, TP27 None
201
243
Forbidden
30 L
B
40
II
3, 6.1
IB2, T11, TP2, TP13,
TP27
150
202
243
1 L
60 L
B
40
Arsenical pesticides, liquid, toxic
6.1 UN2994
I
6.1
T14, TP2, TP13, TP27 None
201
243
1 L
30 L
B
40
II
6.1
IB2, T11, TP2, TP13,
TP27
153
202
243
5 L
60 L
B
40
III
6.1
IB3, T7, TP2, TP28 153
203
241
60 L
220 L
A
40
Arsenical pesticides, liquid, toxic,
flammable, flash point not less
than 23 degrees C
6.1 UN2993
I
6.1, 3
T14, TP2, TP13, TP27 None
201
243
1 L
30 L
B
40
II
6.1, 3
IB2, T11, TP2, TP13,
TP27
153
202
243
5 L
60 L
B
40
III
6.1, 3
B1, IB3, T7, TP2, TP28 153
203
242
60 L
220 L
A
40
Arsenical pesticides, solid, toxic
6.1 UN2759
I
6.1
IB7, IP1, T6, TP33 None
211
242
5 kg
50 kg
A
40
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
40
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
40
Arsenious acid, solid, see Arsenic
trioxide
Arsenious and mercuric iodide solu-
tion, see Arsenic compounds, liq-
uid, n.o.s.
Arsine
2.3 UN2188
2.3,
2.1
1 None
192
245
Forbidden
Forbidden
D
40
Arsine, adsorbed
2.3 UN3522
......
2.3,
2.1
1 None
302c
None
Forbidden
Forbidden
D
G
Articles containing a substance lia-
ble to spontaneous combustion,
n.o.s.
4.2 UN3542
......
4.2
131, 391 None
214
214
Forbidden
Forbidden
............
178
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
G
Articles containing a substance
which in contact with water emits
flammable gases, n.o.s.
4.3 UN3543
......
4.3
131, 391 None
214
214
Forbidden
Forbidden
............
G
Articles containing corrosive sub-
stance, n.o.s.
8 UN3547
......
8
391 None
232
232
Forbidden
Forbidden
B
............
G
Articles containing flammable gas,
n.o.s.
2.1 UN3537
......
2.1
391 None
232
232
Forbidden
Forbidden
D
............
G
Articles containing flammable liquid,
n.o.s.
3 UN3540
......
3
391 None
232
232
Forbidden
Forbidden
B
............
G
Articles containing flammable solid,
n.o.s.
4.1 UN3541
......
4.1
391 None
232
232
Forbidden
Forbidden
B
............
G
Articles containing miscellaneous
dangerous goods, n.o.s.
9 UN3548
......
9
391 None
232
232
Forbidden
Forbidden
A
............
G
Articles containing non-flammable,
non-toxic gas, n.o.s.
2.2 UN3538
......
2.2
391 None
232
232
Forbidden
Forbidden
A
............
G
Articles containing organic peroxide,
n.o.s.
5.2 UN3545
......
5.2
131, 391 None
214
214
Forbidden
Forbidden
............
G
Articles containing oxidizing sub-
stance, n.o.s.
5.1 UN3544
......
5.1
131, 391 None
214
214
Forbidden
Forbidden
............
G
Articles containing toxic gas, n.o.s.
2.3 UN3539
......
2.3
131, 391 None
214
214
Forbidden
Forbidden
............
G
Articles containing toxic substance,
n.o.s.
6.1 UN3546
......
6.1
391 None
232
232
Forbidden
Forbidden
B
............
Articles, explosive, extremely insen-
sitive or Articles, EEI
1.6N UN0486
......
1.6N
........................................
None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s
1.4S UN0349
......
1.4S
101, 148, 347, 382 None
62
None
25 kg
100 kg
01
25
G
Articles, explosive, n.o.s.
1.4B UN0350
......
1.4B
101 None
62
None
Forbidden
Forbidden
05
25
G
Articles, explosive, n.o.s.
1.4C UN0351
......
1.4C
101 None
62
None
Forbidden
75 kg
02
25
G
Articles, explosive, n.o.s.
1.4D UN0352
......
1.4D
101 None
62
None
Forbidden
75 kg
02
25
G
Articles, explosive, n.o.s.
1.4G UN0353
......
1.4G
101 None
62
None
Forbidden
75 kg
02
25
G
Articles, explosive, n.o.s.
1.1L UN0354
......
1.1L
101 None
62
None
Forbidden
Forbidden
02
25,
14E,
15E
G
Articles, explosive, n.o.s.
1.2L UN0355
......
1.2L
101 None
62
None
Forbidden
Forbidden
05
25,
14E,
15E
G
Articles, explosive, n.o.s.
1.3L UN0356
......
1.3L
101 None
62
None
Forbidden
Forbidden
05
25,
14E,
15E
179
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
G
Articles, explosive, n.o.s
1.1C UN0462
......
1.1C
101 None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s
1.1D UN0463
......
1.1D
101 None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s
1.1E UN0464
......
1.1E
101 None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s
1.1F UN0465
......
1.1F
101 None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s
1.2C UN0466
......
1.2C
101 None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s
1.2D UN0467
......
1.2D
101 None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s
1.2E UN0468
......
1.2E
101 None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s
1.2F UN0469
......
1.2F
101 None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s
1.3C UN0470
......
1.3C
101 None
62
None
Forbidden
Forbidden
03
25
G
Articles, explosive, n.o.s.
1.4E UN0471
......
1.4E
101 None
62
None
Forbidden
75 kg
03
25
G
Articles, explosive, n.o.s
1.4F UN0472
......
1.4F
101 None
62
None
Forbidden
Forbidden
03
25
Articles, pressurized pneumatic or
hydraulic containing non-flam-
mable gas
2.2 UN3164
......
2.2
371 306
302, 304
None
No limit
No limit
A
Articles, pyrophoric
1.2L UN0380
......
1.2L
........................................
None
62
None
Forbidden
Forbidden
05
25,
14E,
15E,
17E
Articles, pyrotechnic for technical
purposes
1.1G UN0428
......
1.1G
........................................
None
62
None
Forbidden
Forbidden
03
25
Articles, pyrotechnic for technical
purposes
1.2G UN0429
......
1.2G
........................................
None
62
None
Forbidden
Forbidden
03
25
Articles, pyrotechnic for technical
purposes
1.3G UN0430
......
1.3G
........................................
None
62
None
Forbidden
Forbidden
03
25
Articles, pyrotechnic for technical
purposes
1.4G UN0431
......
1.4G
381 None
62
None
Forbidden
75 kg
02
25
Articles, pyrotechnic for technical
purposes
1.4S UN0432
......
1.4S
........................................
None
62
None
25 kg
100 kg
01
25
D
Asbestos
9 NA2212
III
9
156, IB8, IP2, IP4 155
216
216,
240
200 kg
200 kg
A
34, 40
G I
Asbestos, amphibole amosite,
tremolite, actinolite, anthophyllite,
or crocidolite
9 UN2212
II
9
156, IB8, IP2, IP4, T3,
TP33
155
216
216,
240
Forbidden
Forbidden
A
34, 40
I
Asbestos, chrysotile
9 UN2590
III
9
156, IB8, IP2, IP3, T1,
TP33
155
216
216,
240
200 kg
200 kg
A
34, 40
Ascaridole (organic peroxide)
Forbidden
D
Asphalt, at or above its flash point
3 NA1999
III
3
IB3, T1, TP3 150
203
247
Forbidden
Forbidden
D
D
Asphalt, cut back, see Tars, liquid,
etc
Automobile, motorcycle, tractor,
other self-propelled vehicle, en-
gine, or other mechanical appa-
ratus, see Vehicles or Battery etc
A,
G
Aviation regulated liquid, n.o.s
9 UN3334
......
9
A35, A189 155
204
450 L
450 L
A
A,
G
Aviation regulated solid, n.o.s
9 UN3335
......
9
A35 155
204
400 kg
400 kg
A
Azaurolic acid (salt of) (dry)
Forbidden
Azido guanidine picrate (dry)
Forbidden
5-Azido-1-hydroxy tetrazole
Forbidden
180
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Azido hydroxy tetrazole (mercury
and silver salts)
Forbidden
3-Azido-1,2-Propylene glycol
dinitrate
Forbidden
Azidodithiocarbonic acid
Forbidden
Azidoethyl nitrate
Forbidden
1-Aziridinylphosphine oxide-(tris),
see Tris-(1-aziridinyl) phosphine
oxide, solution
Azodicarbonamide
4.1 UN3242
II
4.1
38, IB8, T3, TP33 151
223
240
Forbidden
Forbidden
D
2, 52,
53, 74
Azotetrazole (dry)
Forbidden
Barium
4.3 UN1400
II
4.3
A19, IB7, IP2, IP21, T3,
TP33, W31, W40
151
212
241
15 kg
50 kg
E
13, 52,
148
Barium alloys, pyrophoric
4.2 UN1854
I
4.2
T21, TP7, TP33, W31 None
181
None
Forbidden
Forbidden
D
13, 148
Barium azide, dry or wetted with
less than 50 percent water, by
mass
1.1A UN0224
......
1.1A,
6.1
111, 117 None
62
None
Forbidden
Forbidden
05
25
Barium azide, wetted with not less
than 50 percent water, by mass
4.1 UN1571
I
4.1,
6.1
162, A2, W31 None
182
None
Forbidden
0.5 kg
D
28, 36
Barium bromate
5.1 UN2719
II
5.1,
6.1
IB8, IP2, IP4, T3, TP33 152
212
242
5 kg
25 kg
A
56, 58
Barium chlorate, solid
5.1 UN1445
II
5.1,
6.1
A9, IB6, IP2, N34, T3,
TP33
152
212
242
5 kg
25 kg
A
56, 58
Barium chlorate, solution
5.1 UN3405
II
5.1,
6.1
A9, IB2, N34, T4, TP1 152
202
243
1 L
5 L
A
56, 58,
133
III
5.1,
6.1
A9, IB2, N34, T4, TP1 152
203
242
2.5 L
30 L
A
56, 58,
133
G
Barium compounds, n.o.s
6.1 UN1564
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Barium cyanide
6.1 UN1565
I
6.1
IB7, IP1, N74, N75, T6,
TP33, W31
None
211
242
5 kg
50 kg
A
40, 52
Barium hypochlorite with more than
22 percent available chlorine
5.1 UN2741
II
5.1,
6.1
A7, A9, IB8, IP2, IP4,
N34, T3, TP33
152
212
None
5 kg
25 kg
B
4, 52,
56, 58,
106
Barium nitrate
5.1 UN1446
II
5.1,
6.1
IB8, IP2, IP4, T3, TP33 152
212
242
5 kg
25 kg
A
Barium oxide
6.1 UN1884
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
181
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Barium perchlorate, solid
5.1 UN1447
II
5.1,
6.1
IB6, IP2, T3, TP33 152
212
242
5 kg
25 kg
A
56, 58
Barium perchlorate, solution
5.1 UN3406
II
5.1,
6.1
IB2, T4, TP1 152
202
243
1 L
5 L
A
56, 58,
133
III
5.1,
6.1
IB2, T4, TP1 152
203
242
2.5 L
30 L
A
56, 58,
133
Barium permanganate
5.1 UN1448
II
5.1,
6.1
IB6, IP2, T3, TP33 152
212
242
5 kg
25 kg
D
56, 58,
138
Barium peroxide
5.1 UN1449
II
5.1,
6.1
A9, IB6, IP2, T3, TP33,
W100
152
212
242
5 kg
25 kg
C
13, 52,
66, 75,
148
Barium selenate, see Selenates or
Selenites
Barium selenite, see Selenates or
Selenites
Batteries, containing sodium
4.3 UN3292
......
4.3
........................................
189
189
189
Forbidden
No limit
A
13, 148
Batteries, dry, containing potassium
hydroxide solid, electric storage
8 UN3028
......
8
237 154
213
None
25 kg
230 kg
A
52
Batteries, dry, sealed, n.o.s.
130
W
Batteries, nickel-metal hydride see
Batteries, dry, sealed, n.o.s. for
nickel-metal hydride batteries
transported by modes other than
vessel
9 UN3496
......
9
340
..................
..................
A
25
Batteries, wet, filled with acid, elec-
tric storage
8 UN2794
......
8
A51 159
159
159
30 kg
No limit
A
53, 58,
146
Batteries, wet, filled with alkali,
electric storage
8 UN2795
......
8
A51 159
159
159
30 kg
No limit
A
52, 146
Batteries, wet, non-spillable, electric
storage
8 UN2800
......
8
........................................
159a
159
159
No limit
No limit
A
Battery fluid, acid
8 UN2796
II
8
A3, A7, B2, B15, IB2,
N6, N34, T8, TP2
154
202
242
1 L
30 L
B
Battery fluid, alkali
8 UN2797
II
8
B2, IB2, N6, T7, TP2,
TP28
154
202
242
1 L
30 L
A
29
Battery lithium type, see Lithium
batteries etc
Battery-powered vehicle or Battery-
powered equipment
9 UN3171
......
9
134, 360 220
220
None
No limit
No limit
A
............
Battery, wet, filled with acid or alkali
with vehicle or mechanical equip-
ment containing an internal com-
bustion engine, see Vehicle, etc.
or Engines, internal combustion,
etc
+
Benzaldehyde
9 UN1990
III
9
IB3, T2, TP1 155
203
241
100 L
220 L
A
Benzene
3 UN1114
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
40
Benzene diazonium chloride (dry)
Forbidden
Benzene diazonium nitrate (dry)
Forbidden
Benzene phosphorus dichloride,
see Phenyl phosphorus dichloride
182
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Benzene phosphorus thiodichloride,
see Phenyl phosphorus
thiodichloride
Benzene sulfonyl chloride
8 UN2225
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
40
Benzene triozonide
Forbidden
Benzenethiol, see Phenyl
mercaptan
Benzidine
6.1 UN1885
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
1, 3, 2-Benzodioxaborole
................
......
A210
Benzol, see Benzene
Benzonitrile
6.1 UN2224
II
6.1
IB2, T7, TP2 153
202
243
5 L
60 L
A
40, 52
Benzoquinone
6.1 UN2587
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
Benzotrichloride
8 UN2226
II
8
B2, IB2, T7, TP2 154
202
242
1 L
30 L
A
40, 53,
58
Benzotrifluoride
3 UN2338
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
40
Benzoxidiazoles (dry)
Forbidden
Benzoyl azide
Forbidden
Benzoyl chloride
8 UN1736
II
8
B2, IB2, T8, TP2, TP13 154
202
242
1 L
30 L
C
40, 53,
58
Benzyl bromide
6.1 UN1737
II
6.1, 8
A3, A7, IB2, N33, N34,
T8, TP2, TP13
None
202
243
1 L
30 L
D
13, 40,
53, 58
Benzyl chloride
6.1 UN1738
II
6.1, 8
A3, A7, B70, IB2, N33,
N42, T8, TP2, TP13
None
202
243
1 L
30 L
D
13, 40,
53, 58
Benzyl chloride unstabilized
6.1 UN1738
II
6.1, 8
A3, A7, B8, B11, IB2,
N33, N34, N43, T8,
TP2, TP13
153
202
243
1 L
30 L
D
13, 40,
53, 58
Benzyl chloroformate
8 UN1739
I
8
B4, N41, T10, TP2,
TP13
None
201
243
Forbidden
2.5 L
D
40, 53,
58
Benzyl iodide
6.1 UN2653
II
6.1
IB2, T7, TP2 153
202
243
5 L
60 L
B
12, 40
Benzyldimethylamine
8 UN2619
II
8, 3
B2, IB2, T7, TP2 154
202
243
1 L
30 L
A
25, 40,
52
Benzylidene chloride
6.1 UN1886
II
6.1
IB2, T7, TP2 153
202
243
5 L
60 L
D
40
G
Beryllium compounds, n.o.s
6.1 UN1566
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Beryllium nitrate
5.1 UN2464
II
5.1,
6.1
IB8, IP2, IP4, T3, TP33 152
212
242
5 kg
25 kg
A
183
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Beryllium, powder
6.1 UN1567
II
6.1,
4.1
IB8, IP2, IP4, T3, TP33,
W100
153
212
242
15 kg
50 kg
A
13,
147,
148
Bicyclo [2,2,1] hepta-2,5-diene, sta-
bilized or 2,5-Norbornadiene, sta-
bilized
3 UN2251
II
3
387, IB2, T7, TP2 150
202
242
5 L
60 L
D
25
Biological substance, Category B
6.2 UN3373
A82 134
199
None
4 L or 4 kg 4 L or 4 kg
A
40
Biphenyl triozonide
Forbidden
Bipyridilium pesticides, liquid, flam-
mable, toxic, flash point less than
23 degrees C
3 UN2782
I
3, 6.1
T14, TP2, TP13, TP27 None
201
243
Forbidden
30 L
E
II
3, 6.1
IB2, T11, TP2, TP13,
TP27
150
202
243
1 L
60 L
B
40
Bipyridilium pesticides, liquid, toxic
6.1 UN3016
I
6.1
T14, TP2, TP13, TP27 None
201
243
1 L
30 L
B
40
II
6.1
IB2, T11, TP2, TP13,
TP27
153
202
243
5 L
60 L
B
40
III
6.1
IB3, T7, TP2, TP28 153
203
241
60 L
220 L
A
40
Bipyridilium pesticides, liquid, toxic,
flammable, flash point not less
than 23 degrees C
6.1 UN3015
I
6.1, 3
T14, TP2, TP13, TP27 None
201
243
1 L
30 L
B
21, 40
II
6.1, 3
IB2, T11, TP2, TP13,
TP27
153
202
243
5 L
60 L
B
21, 40
III
6.1, 3
B1, IB3, T7, TP2, TP28 153
203
242
60 L
220 L
A
21, 40
Bipyridilium pesticides, solid, toxic
6.1 UN2781
I
6.1
IB7, IP1, T6, TP33 None
211
242
5 kg
50 kg
A
40
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
40
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
40
Bis (Aminopropyl) piperazine, see
Corrosive liquid, n.o.s.
Bisulfate, aqueous solution
8 UN2837
II
8
A7, B2, IB2, N34, T7,
TP2
154
202
242
1 L
30 L
A
III
8
A7, IB3, N34, T4, TP1 154
203
241
5 L
60 L
A
Bisulfites, aqueous solutions, n.o.s.
8 UN2693
III
8
IB3, T7, TP1, TP28 154
203
241
5 L
60 L
A
40, 52
Black powder, compressed or Gun-
powder, compressed or Black
powder, in pellets or Gunpowder,
in pellets
1.1D UN0028
......
1.1D
........................................
None
62
None
Forbidden
Forbidden
04
25
Black powder or Gunpowder,
granular or as a meal
1.1D UN0027
......
1.1D
........................................
None
62
None
Forbidden
Forbidden
04
25
D
Black powder for small arms
4.1 NA0027
I
4.1
70 None
170
None
Forbidden
Forbidden
E
Blasting agent, n.o.s., see Explo-
sives, blasting etc
Blasting cap assemblies, see Deto-
nator assemblies, non-electric, for
blasting
Blasting caps, electric, see Deto-
nators, electric for blasting
Blasting caps, non-electric, see Det-
onators, non-electric, for blasting
Bleaching powder, see Calcium hy-
pochlorite mixtures, etc
184
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Bombs, photo-flash
1.1F UN0037
......
1.1F
........................................
62
None
Forbidden
Forbidden
03
25
Bombs, photo-flash
1.1D UN0038
......
1.1D
........................................
62
62
Forbidden
Forbidden
03
25
Bombs, photo-flash
1.2G UN0039
......
1.2G
........................................
62
62
Forbidden
Forbidden
03
25
Bombs, photo-flash
1.3G UN0299
......
1.3G
........................................
62
62
Forbidden
Forbidden
03
25
Bombs, smoke, non-explosive, with
corrosive liquid, without initiating
device
8 UN2028
II
8
None
160
None
Forbidden
50 kg
E
40
Bombs, with bursting charge
1.1F UN0033
......
1.1F
........................................
62
None
Forbidden
Forbidden
03
25
Bombs, with bursting charge
1.1D UN0034
......
1.1D
........................................
62
62
Forbidden
Forbidden
03
25
Bombs, with bursting charge
1.2D UN0035
......
1.2D
........................................
62
62
Forbidden
Forbidden
03
25
Bombs, with bursting charge
1.2F UN0291
......
1.2F
........................................
62
None
Forbidden
Forbidden
03
25
Bombs with flammable liquid, with
bursting charge
1.1J UN0399
......
1.1J
........................................
62
None
Forbidden
Forbidden
05
25,
23E
Bombs with flammable liquid, with
bursting charge
1.2J UN0400
......
1.2J
........................................
62
None
Forbidden
Forbidden
05
25,
23E
Boosters with detonator
1.1B UN0225
......
1.1B
........................................
None
62
None
Forbidden
Forbidden
05
25
Boosters with detonator
1.2B UN0268
......
1.2B
........................................
None
62
None
Forbidden
Forbidden
05
25
Boosters, without detonator
1.1D UN0042
......
1.1D
148 None
62
None
Forbidden
Forbidden
03
25
Boosters, without detonator
1.2D UN0283
......
1.2D
........................................
None
62
None
Forbidden
Forbidden
03
25
Borate and chlorate mixtures, see
Chlorate and borate mixtures
Borneol
4.1 UN1312
III
4.1
A1, IB8, IP3, T1, TP33 151
213
240
25 kg
100 kg
A
+
Boron tribromide
8 UN2692
I
8, 6.1
2, B9, B14, B32, N34,
T20, TP2, TP13, TP38,
TP45
None
227
244
Forbidden
Forbidden
C
12, 25,
53, 58
Boron trichloride
2.3 UN1741
2.3, 8
3, B9, B14 None
304
314
Forbidden
Forbidden
D
25, 40
Boron trifluoride
2.3 UN1008
......
2.3, 8
2, 238, B9, B14 None
302
314,
315
Forbidden
Forbidden
D
40
Boron trifluoride acetic acid com-
plex, liquid
8 UN1742
II
8
B2, B6, IB2, T8, TP2 154
202
242
1 L
30 L
A
53, 58
Boron trifluoride acetic acid com-
plex, solid
8 UN3419
II
8
B2, B6, IB8, IP2, IP4,
T3, TP33
154
212
240
15 kg
50 kg
A
53, 58
Boron trifluoride, adsorbed
2.3 UN3519
......
2.3, 8
2, B9, B14 None
302c
None
Forbidden
Forbidden
D
40
Boron trifluoride diethyl etherate
8 UN2604
I
8, 3
A19, T10, TP2, W31 None
201
243
0.5 L
2.5 L
D
40, 53,
58
Boron trifluoride dihydrate
8 UN2851
II
8
IB2, T7, TP2 154
212
240
15 kg
50 kg
B
12, 25,
40, 53,
58
185
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Boron trifluoride dimethyl etherate
4.3 UN2965
I
4.3, 8,
3
A19, T10, TP2, TP7,
TP13, W31
None
201
243
Forbidden
1 L
D
21, 25,
40, 49,
100
Boron trifluoride propionic acid com-
plex, liquid
8 UN1743
II
8
B2, IB2, T8, TP2 154
202
242
1 L
30 L
A
53, 58
Boron trifluoride propionic acid com-
plex, solid
8 UN3420
II
8
B2, IB8, IP2, IP4, T3,
TP33
154
212
240
15 kg
50 kg
A
53, 58
Box toe gum, see Nitrocellulose etc
G
Bromates, inorganic, aqueous solu-
tion, n.o.s
5.1 UN3213
II
5.1
350, IB2, T4, TP1 152
202
242
1 L
5 L
B
56, 58,
133
III
5.1
350, IB2, T4, TP1 152
203
241
2.5 L
30 L
B
56, 58,
133
G
Bromates, inorganic, n.o.s
5.1 UN1450
II
5.1
350, IB8, IP2, IP4, T3,
TP33
152
212
242
5 kg
25 kg
A
56, 58
+
Bromine
8 UN1744
I
8, 6.1
1, B9, B85, N34, N43,
T22, TP2, TP10, TP13
None
226
249
Forbidden
Forbidden
D
12, 25,
40, 53,
58, 66,
74, 89,
90
Bromine azide
Forbidden
Bromine chloride
2.3 UN2901
2.3, 8,
5.1
2, B9, B14, N86 None
304
314,
315
Forbidden
Forbidden
D
40, 89,
90
+
Bromine pentafluoride
5.1 UN1745
I
5.1,
6.1,
8
1, B9, B14, B30, T22,
TP2, TP13, TP38, TP44
None
228
244
Forbidden
Forbidden
D
25, 40,
53, 58,
66, 90
+
Bromine solutions
8 UN1744
I
8, 6.1
1, B9, B85, N34, N43,
T22, TP2, TP10, TP13
None
226
249
Forbidden
Forbidden
D
12, 25,
40, 53,
58, 66,
74, 89,
90
+
Bromine solutions
8 UN1744
I
8, 6.1
2, B9, B85, N34, N43,
T22, TP2, TP10, TP13
None
227
249
Forbidden
Forbidden
D
12, 25,
40, 53,
58, 66,
74, 89,
90
+
Bromine trifluoride
5.1 UN1746
I
5.1,
6.1,
8
2, B9, B14, B32, T22,
TP2, TP13, TP38, TP45
None
228
244
Forbidden
Forbidden
D
25, 40,
53, 58,
66, 90
4-Bromo-1,2-dinitrobenzene
Forbidden
4-Bromo-1,2-dinitrobenzene (unsta-
ble at 59 degrees C)
Forbidden
1-Bromo-3-chloropropane
6.1 UN2688
III
6.1
IB3, T4, TP1 153
203
241
60 L
220 L
A
1-Bromo-3-methylbutane
3 UN2341
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
1-Bromo-3-nitrobenzene (unstable
at 56 degrees C)
Forbidden
2-Bromo-2-nitropropane-1,3-diol
4.1 UN3241
III
4.1
46, IB8, IP3 151
213
None
25 kg
50 kg
C
12, 25,
40
Bromoacetic acid, solid
8 UN3425
II
8
A7, IB8, IP2, IP4, N34,
T3, TP33
154
212
240
15 kg
50 kg
A
53, 58
186
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Bromoacetic acid solution
8 UN1938
II
8
A7, B2, IB2, T7, TP2 154
202
242
1 L
30 L
A
40, 53,
58
III
8
B2, IB3, T7, TP2 154
203
241
5 L
60 L
A
40, 53,
58
+
Bromoacetone
6.1 UN1569
II
6.1, 3
2, T20, TP2, TP13 None
193
245
Forbidden
Forbidden
D
40
Bromoacetyl bromide
8 UN2513
II
8
B2, IB2, T8, TP2 154
202
242
1 L
30 L
C
40, 53,
58
Bromobenzene
3 UN2514
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Bromobenzyl cyanides, liquid
6.1 UN1694
I
6.1
T14, TP2, TP13, W31 None
201
243
Forbidden
30 L
D
12, 25,
40, 52
Bromobenzyl cyanides, solid
6.1 UN3449
I
6.1
T6, TP33, W31 None
211
242
5 kg
50 kg
D
12, 25,
40, 52
1-Bromobutane
3 UN1126
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
40
2-Bromobutane
3 UN2339
II
3
B1, IB2, T4, TP1 150
202
242
5 L
60 L
B
40
Bromochloromethane
6.1 UN1887
III
6.1
IB3, T4, TP1 153
203
241
60 L
220 L
A
2-Bromoethyl ethyl ether
3 UN2340
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
40
Bromoform
6.1 UN2515
III
6.1
IB3, T4, TP1 153
203
241
60 L
220 L
A
12, 25,
40
Bromomethylpropanes
3 UN2342
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
2-Bromopentane
3 UN2343
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
Bromopropanes
3 UN2344
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
40
III
3
IB3, T2, TP1 150
203
242
60 L
220 L
A
3-Bromopropyne
3 UN2345
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
D
40
Bromosilane
Forbidden
Bromotoluene-alpha, see Benzyl
bromide
Bromotrifluoroethylene
2.1 UN2419
2.1
None
304
314,
315
Forbidden
150 kg
B
40
Bromotrifluoromethane or Refrig-
erant gas, R 13B1.
2.2 UN1009
2.2
T50 306
304
314,
315
75 kg
150 kg
A
Brucine
6.1 UN1570
I
6.1
IB7, IP1, T6, TP33 None
211
242
5 kg
50 kg
A
Bursters, explosive
1.1D UN0043
......
1.1D
........................................
None
62
None
Forbidden
Forbidden
03
25
Butadienes, stabilized or
Butadienes and Hydrocarbon
mixture, stabilized containing
more than 40% butadienes
2.1 UN1010
......
2.1
387, T50 306
304
314,
315
Forbidden
150 kg
B
25, 40
Butane see also Petroleum gases,
liquefied
2.1 UN1011
2.1
19, T50 306
304
314,
315
Forbidden
150 kg
E
40
187
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Butane, butane mixtures and mix-
tures having similar properties in
cartridges each not exceeding
500 grams, see Receptacles, etc
Butanedione
3 UN2346
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
1,2,4-Butanetriol trinitrate
Forbidden
Butanols
3 UN1120
II
3
IB2, T4, TP1, TP29 150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
tert-Butoxycarbonyl azide
Forbidden
Butyl acetates
3 UN1123
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Butyl acid phosphate
8 UN1718
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
53, 58
Butyl acrylates, stabilized
3 UN2348
III
3
387, B1, IB3, T2, TP1 150
203
242
60 L
220 L
C
25
Butyl alcohols, see Butanols
Butyl benzenes
3 UN2709
III
3
B1, IB3, T2, TP2 150
203
242
60 L
220 L
A
n-Butyl bromide, see 1-
Bromobutane
n-Butyl chloride, see Chlorobutanes
n-Butyl chloroformate
6.1 UN2743
I
6.1, 8,
3
2, B9, B14, B32, T20,
TP2, TP13, TP38, TP45
None
227
244
Forbidden
Forbidden
A
12, 13,
21, 25,
40, 53,
58, 100
Butyl ethers, see Dibutyl ethers
Butyl ethyl ether, see Ethyl butyl
ether
n-Butyl formate
3 UN1128
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
tert-Butyl hydroperoxide, with more
than 90 percent with water
Forbidden
tert-Butyl hypochlorite
4.2 UN3255
I
4.2, 8
........................................
None
211
243
Forbidden
Forbidden
D
40
N-n-Butyl imidazole
6.1 UN2690
II
6.1
IB2, T7, TP2 153
202
243
5 L
60 L
A
tert-Butyl isocyanate
6.1 UN2484
I
6.1, 3
1, B9, B14, B30, T20,
TP2, TP13, TP38, TP44
None
226
244
Forbidden
Forbidden
D
40
n-Butyl isocyanate
6.1 UN2485
I
6.1, 3
2, B9, B14, B32, B77,
T20, TP2, TP13, TP38,
TP45
None
227
244
Forbidden
Forbidden
D
40
Butyl mercaptan
3 UN2347
II
3
A3, IB2, T4, TP1 150
202
242
5 L
60 L
D
52, 95,
102
n-Butyl methacrylate, stabilized
3 UN2227
III
3
387, B1, IB3, T2, TP1 150
203
242
60 L
220 L
C
25
Butyl methyl ether
3 UN2350
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
Butyl nitrites
3 UN2351
I
3
T11, TP1, TP8, TP27 150
201
243
1 L
30 L
E
40
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
40
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
40
tert-Butyl peroxyacetate, with more
than 76 percent in solution
Forbidden
n-Butyl peroxydicarbonate, with
more than 52 percent in solution
Forbidden
tert-Butyl peroxyisobutyrate, with
more than 77 percent in solution
Forbidden
Butyl phosphoric acid, see Butyl
acid phosphate
188
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Butyl propionates
3 UN1914
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
5-tert-Butyl-2,4,6-trinitro-m-xylene or
Musk xylene
4.1 UN2956
III
4.1
159 151
223
None
Forbidden
Forbidden
D
12, 25,
40, 127
Butyl vinyl ether, stabilized
3 UN2352
II
3
387, IB2, T4, TP1 150
202
242
5 L
60 L
C
25, 40
n-Butylamine
3 UN1125
II
3, 8
IB2, T7, TP1 150
202
242
1 L
5 L
B
40, 52
N-Butylaniline
6.1 UN2738
II
6.1
IB2, T7, TP2 153
202
243
5 L
60 L
A
74
tert-Butylcyclohexylchloroformate
6.1 UN2747
III
6.1
IB3, T4, TP1 153
203
241
60 L
220 L
A
12, 13,
25
Butylene see also Petroleum gases,
liquefied
2.1 UN1012
2.1
19, T50 306
304
314,
315
Forbidden
150 kg
E
40
1,2-Butylene oxide, stabilized
3 UN3022
II
3
387, IB2, T4, TP1 150
202
242
5 L
60 L
C
25, 27,
49
Butyltoluenes
6.1 UN2667
III
6.1
IB3, T4, TP1 153
203
241
60 L
220 L
A
Butyltrichlorosilane
8 UN1747
II
8, 3
A7, B2, B6, N34, T10,
TP2, TP7, TP13
None
206
243
Forbidden
30 L
C
40, 53,
58
1,4-Butynediol
6.1 UN2716
III
6.1
A1, IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
C
52, 53,
70
Butyraldehyde
3 UN1129
II
3
IB2, T4, TP1 150
202
242
5 L
60 L
B
Butyraldoxime
3 UN2840
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Butyric acid
8 UN2820
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
12, 25,
53, 58
Butyric anhydride
8 UN2739
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
53, 58
Butyronitrile
3 UN2411
II
3, 6.1
IB2, T7, TP1, TP13 150
202
243
1 L
60 L
E
40
Butyryl chloride
3 UN2353
II
3, 8
IB2, T8, TP2, TP13 150
202
243
1 L
5 L
C
40, 53,
58
Cacodylic acid
6.1 UN1572
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
E
52, 53,
58
G
Cadmium compounds
6.1 UN2570
I
6.1
IB7, IP1, T6, TP33 None
211
242
5 kg
50 kg
A
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
Caesium hydroxide
8 UN2682
II
8
IB8, IP2, IP4, T3, TP33 154
212
240
15 kg
50 kg
A
29, 52.
Caesium hydroxide solution
8 UN2681
II
8
B2, IB2, T7, TP2 154
202
242
1 L
30 L
A
29, 52
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
29, 52
Calcium
4.3 UN1401
II
4.3
IB7, IP2, IP21, T3,
TP33, W31, W40
151
212
241
15 kg
50 kg
E
13, 52,
148
Calcium arsenate
6.1 UN1573
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
Calcium arsenate and calcium
arsenite, mixtures, solid
6.1 UN1574
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
189
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Calcium bisulfite solution, see
Bisulfites, aqueous solutions,
n.o.s.
Calcium carbide
4.3 UN1402
I
4.3
A1, A8, B55, B59, IB4,
IP1, N34, T9, TP7,
TP33, W31
None
211
242
Forbidden
15 kg
B
13, 52,
148
II
4.3
A1, A8, B55, B59, IB7,
IP2, IP21, N34, T3,
TP33, W31, W40
151
212
241
15 kg
50 kg
B
13, 52,
148
Calcium chlorate
5.1 UN1452
II
5.1
A9, IB8, IP2, IP4, N34,
T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Calcium chlorate aqueous solution
5.1 UN2429
II
5.1
A2, IB2, N41, T4, TP1 152
202
242
1 L
5 L
B
56, 58,
133
III
5.1
A2, IB2, N41, T4, TP1 152
203
241
2.5 L
30 L
B
56, 68,
133
Calcium chlorite
5.1 UN1453
II
5.1
A9, IB8, IP2, IP4, N34,
T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Calcium cyanamide with more than
0.1 percent of calcium carbide
4.3 UN1403
III
4.3
A1, A19, IB8, IP4, T1,
TP33, W31
151
213
241
25 kg
100 kg
A
13, 52,
148
Calcium cyanide
6.1 UN1575
I
6.1
IB7, IP1, N79, N80, T6,
TP33, W31
None
211
242
5 kg
50 kg
A
40, 52
Calcium dithionite or Calcium hy-
drosulfite
4.2 UN1923
II
4.2
A19, A20, IB6, IP2, T3,
TP33, W31
None
212
241
15 kg
50 kg
E
13
Calcium hydride
4.3 UN1404
I
4.3
A19, N40, W31 None
211
242
Forbidden
15 kg
E
13, 52,
148
Calcium hydrosulfite, see Calcium
dithionite
Calcium hypochlorite, dry, corrosive
or Calcium hypochlorite mixture,
dry, corrosive with more than
39% available chlorine (8.8%
available oxygen)
5.1 UN3485
II
5.1, 8
165, 166, A7, A9, IB8,
IP2, IP4, IP13, N34, W9
152
212
None
5 kg
25 kg
D
4, 25,
52, 56,
58, 69,
142
Calcium hypochlorite, dry or Cal-
cium hypochlorite mixture dry
with more than 39% available
chlorine (8.8% available oxygen)
5.1 UN1748
II
5.1
165, 166, A7, A9, IB8,
IP2, IP4, IP13, N34, W9
152
212
None
5 kg
25 kg
D
4, 25,
52, 56,
58, 69,
142
III
5.1
165, 171, A7, A9, IB8,
IP4, IP13, N34, W9
152
213
240
25 kg
100 kg
D
4, 25,
52, 56,
58, 69,
142
Calcium hypochlorite, hydrated, cor-
rosive or Calcium hypochlorite,
hydrated mixture, corrosive with
not less than 5.5% but not more
than 16% water
5.1 UN3487
II
5.1, 8
165, IB8, IP2, IP4, IP13,
W9
152
212
240
5 kg
25 kg
D
4, 25,
52, 56,
58, 69,
142
III
5.1, 8
165, IB8, IP4, W9 152
213
240
25 kg
100 kg
D
4, 25,
52, 56,
58, 69,
142
190
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Calcium hypochlorite, hydrated or
Calcium hypochlorite, hydrated
mixture, with not less than 5.5%
but not more than 16% water
5.1 UN2880
II
5.1
165, IB8, IP2, IP4, IP13,
W9
152
212
240
5 kg
25 kg
D
4, 25,
52, 56,
58, 69,
142
III
5.1
165, 171, IB8, IP4, IP13,
W9
152
213
240
25 kg
100 kg
D
4, 25,
52, 56,
58, 69,
142
Calcium hypochlorite mixture, dry,
corrosive with more than 10% but
not more than 39% available
chlorine
5.1 UN3486
III
5.1, 8
165, A1, A29, IB8, IP3,
IP13, N34, W9, W10
152
213
240
5 kg
25 kg
D
4, 25,
52, 56,
58, 69,
142
Calcium hypochlorite mixture, dry,
with more than 10% but not more
than 39% available chlorine
5.1 UN2208
III
5.1
165, A1, A29, IB8, IP3,
IP13, N34, W9, W10
152
213
240
25 kg
100 kg
D
4, 25,
52, 56,
58, 69,
142
Calcium manganese silicon
4.3 UN2844
III
4.3
A1, A19, IB8, IP4, T1,
TP33, W31
151
213
241
25 kg
100 kg
A
13, 52,
85,
103,
148
Calcium nitrate
5.1 UN1454
III
5.1
34, B120, IB8, IP3, T1,
TP33
152
213
240
25 kg
100 kg
A
............
A
Calcium oxide
8 UN1910
III
8
IB8, IP3, T1, TP33 154
213
240
25 kg
100 kg
A
Calcium perchlorate
5.1 UN1455
II
5.1
IB6, IP2, T3, TP33 152
212
242
5 kg
25 kg
A
56, 58
Calcium permanganate
5.1 UN1456
II
5.1
IB6, IP2, T3, TP33 152
212
242
5 kg
25 kg
D
56, 58,
138
Calcium peroxide
5.1 UN1457
II
5.1
IB6, IP2, T3, TP33,
W100
152
212
242
5 kg
25 kg
C
13, 52,
66, 75,
148
Calcium phosphide
4.3 UN1360
I
4.3,
6.1
A8, A19, N40, W31 None
211
242
Forbidden
15 kg
E
13, 40,
52, 85,
148
Calcium, pyrophoric or Calcium al-
loys, pyrophoric
4.2 UN1855
I
4.2
W31 None
187
None
Forbidden
Forbidden
D
13, 148
Calcium resinate
4.1 UN1313
III
4.1
A1, A19, IB6, T1, TP33 151
213
240
25 kg
100 kg
A
Calcium resinate, fused
4.1 UN1314
III
4.1
A1, A19, IB4, T1, TP33 151
213
240
25 kg
100 kg
A
Calcium selenate, see Selenates or
Selenites
191
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Calcium silicide
4.3 UN1405
II
4.3
A19, IB7, IP2, IP21, T3,
TP33, W31
151
212
241
15 kg
50 kg
B
13, 52,
85,
103,
148
III
4.3
A1, A19, IB8, IP21, T1,
TP33, W31
151
213
241
25 kg
100 kg
B
13, 52,
85,
103,
148
Camphor oil
3 UN1130
III
3
B1, IB3, T2, TP1 150
203
242
60 L
220 L
A
Camphor, synthetic
4.1 UN2717
III
4.1
A1, IB8, IP3, T1, TP33 151
213
240
25 kg
100 kg
A
Cannon primers, see Primers, tubu-
lar
Capacitor, asymmetric with an en-
ergy storage capacity greater
than 0.3 Wh
9 UN3508
......
9
372 176
176
176
No limit
No Limit
A
Capacitor, electric double layer with
an energy storage capacity great-
er than 0.3 Wh
9 UN3499
......
9
361 176
176
176
No limit
No limit
A
Caproic acid
8 UN2829
III
8
IB3, T4, TP1 154
203
241
5 L
60 L
A
53, 58
Caps, blasting, see Detonators, etc
Carbamate pesticides, liquid, flam-
mable, toxic, flash point less than
23 degrees C
3 UN2758
I
3, 6.1
T14, TP2, TP13, TP27 None
201
243
Forbidden
30 L
B
40
II
3, 6.1
IB2, T11, TP2, TP13,
TP27
150
202
243
1 L
60 L
B
40
Carbamate pesticides, liquid, toxic
6.1 UN2992
I
6.1
T14, TP2, TP13, TP27 None
201
243
1 L
30 L
B
40
II
6.1
IB2, T11, TP2, TP13,
TP27
153
202
243
5 L
60 L
B
40
III
6.1
IB3, T7, TP2, TP28 153
203
241
60 L
220 L
A
40
Carbamate pesticides, liquid, toxic,
flammable, flash point not less
than 23 degrees C
6.1 UN2991
I
6.1, 3
T14, TP2, TP13, TP27 None
201
243
1 L
30 L
B
40
II
6.1, 3
IB2, T11, TP2, TP13,
TP27
153
202
243
5 L
60 L
B
40
III
6.1, 3
B1, IB3, T7, TP2, TP28 153
203
242
60 L
220 L
A
40
Carbamate pesticides, solid, toxic
6.1 UN2757
I
6.1
IB7, IP1, T6, TP33 None
211
242
5 kg
50 kg
A
40
II
6.1
IB8, IP2, IP4, T3, TP33 153
212
242
25 kg
100 kg
A
40
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
40
Carbolic acid, see Phenol, solid or
Phenol, molten
Carbolic acid solutions, see Phenol
solutions
I
Carbon, activated
4.2 UN1362
III
4.2
IB8, IP3, T1, TP33, W31 None
213
241
0.5 kg
0.5 kg
A
12, 25
I
Carbon, animal or vegetable origin
4.2 UN1361
II
4.2
IB6, T3, TP33 None
212
242
Forbidden
Forbidden
A
12, 25
III
4.2
IB8, IP3, T1, TP33 None
213
241
Forbidden
Forbidden
A
12, 25
Carbon bisulfide, see Carbon disul-
fide
Carbon dioxide
2.2 UN1013
2.2
306
302, 304
302,
314,
315
75 kg
150 kg
A
192
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Carbon dioxide, refrigerated liquid
2.2 UN2187
2.2
T75, TP5 306
304
314,
315
50 kg
500 kg
D
A W
Carbon dioxide, solid or Dry ice
9 UN1845
None
217
217
240
200 kg
200 kg
C
40
Carbon disulfide
3 UN1131
I
3, 6.1
B16, T14, TP2, TP7,
TP13, W31
None
201
243
Forbidden
Forbidden
D
40, 78,
115
Carbon monoxide, compressed
2.3 UN1016
2.3,
2.1
4 None
302
314,
315
Forbidden
25 kg
D
40
D
Carbon monoxide, refrigerated liq-
uid (cryogenic liquid)
2.3 NA9202
2.3,
2.1
4, T75, TP5 None
316
318
Forbidden
Forbidden
D
Carbon tetrabromide
6.1 UN2516
III
6.1
IB8, IP3, T1, TP33 153
213
240
100 kg
200 kg
A
25
Carbon tetrachloride
6.1 UN1846
II
6.1
IB2, N36, T7, TP2 153
202
243
5 L
60 L
A
40
Carbonyl chloride, see Phosgene
Carbonyl fluoride
2.3 UN2417
2.3, 8
2 None
302
None
Forbidden
Forbidden
D
40
Carbonyl sulfide
2.3 UN2204
2.3,
2.1
3, B14 None
304
314,
315
Forbidden
Forbidden
D
40
Cartridge cases, empty primed, see
Cases, cartridge, empty, with
primer
Cartridges, actuating, for aircraft
ejector seat catapult, fire extin-
guisher, canopy removal or appa-
ratus, see Cartridges, power de-
vice
Cartridges, explosive, see Charges,
demolition
Cartridges, sporting, see Cartridges
for weapons, inert projectile, or
Cartridges, small arms
Cartridges, flash
1.1G UN0049
......
1.1G
........................................
None
62
None
Forbidden
Forbidden
03
25
Cartridges, flash
1.3G UN0050
......
1.3G
........................................
None
62
None
Forbidden
75 kg
03
25
Cartridges for weapons, blank
1.1C UN0326
......
1.1C
........................................
None
62
None
Forbidden
Forbidden
03
25
Cartridges for weapons, blank
1.2C UN0413
......
1.2C
........................................
None
62
None
Forbidden
Forbidden
03
25
Cartridges for weapons, blank or
Cartridges, small arms, blank
1.3C UN0327
......
1.3C
........................................
None
62
None
Forbidden
Forbidden
03
25
Cartridges for weapons, blank or
Cartridges, small arms, blank
1.4C UN0338
......
1.4C
........................................
None
62
None
Forbidden
75 kg
02
25
193
Pipeline and Haz. Matls. Safety Admin., DOT
§
172.101
Cartridges for weapons, blank or
Cartridges, small arms, blank or
Cartridges for tools, blank
1.4S UN0014
......
None
........................................
63
62
None
25 kg
100 kg
01
25
Cartridges for weapons, inert pro-
jectile
1.2C UN0328
......
1.2C
........................................
None
62
62
Forbidden
Forbidden
03
25
Cartridges for weapons, inert pro-
jectile or Cartridges, small arms
1.4S UN0012
......
None
........................................
63
62
None
25 kg
100 kg
01
25
Cartridges for weapons, inert pro-
jectile or Cartridges, small arms
1.4C UN0339
......
1.4C
........................................
None
62
None
Forbidden
75 kg
02
25
Cartridges for weapons, inert pro-
jectile or Cartridges, small arms
1.3C UN0417
......
1.3C
........................................
None
62
None
Forbidden
Forbidden
03
25
Cartridges for weapons, with burst-
ing charge
1.1F UN0005
......
1.1F
........................................
None
62
None
Forbidden
Forbidden
03
25
Cartridges for weapons, with burst-
ing charge
1.1E UN0006
......
1.1E
........................................
None
62
62
Forbidden
Forbidden
03
25
Cartridges for weapons, with burst-
ing charge
1.2F UN0007
......
1.2F
........................................
None
62
None
Forbidden
Forbidden
03
25
Cartridges for weapons, with burst-
ing charge
1.2E UN0321
......
1.2E
........................................
None
62
62
Forbidden
Forbidden
03
25
Cartridges for weapons, with burst-
ing charge
1.4F UN0348
......
1.4F
........................................
None
62
None
Forbidden
Forbidden
03
25
Cartridges for weapons, with burst-
ing charge
1.4E UN0412
......
1.4E
........................................
None
62
62
Forbidden
75 kg
03
25
Cartridges, oil well
1.3C UN0277
......
1.3C
........................................
None
62
62
Forbidden
Forbidden
03
25
Cartridges, oil well
1.4C UN0278
......
1.4C
........................................
None
62
62
Forbidden
75 kg
02
25
Cartridges, power device
1.3C UN0275
......
1.3C
........................................
None
62
62
Forbidden
75 kg
03
25
Cartridges, power device
1.4C UN0276
......
1.4C
110 None
62
62
Forbidden
75 kg
02
25
Cartridges, power device
1.4S UN0323
......
1.4S
110, 347 63
62
62
25 kg
100 kg
01
25
Cartridges, power device
1.2C UN0381
......
1.2C
........................................
None
62
62
Forbidden
Forbidden
03
25
Cartridges, safety, blank, see Car-
tridges for weapons, blank (UN
0014)
Cartridges, safety, see Cartriges for
weapons, inert projectile, or Car-
tridges, small arms or Cartridges,
power device (UN 0323)
Cartridges, signal
1.3G UN0054
......
1.3G
........................................
None
62
None
Forbidden
75 kg
03
25
Cartridges, signal
1.4G UN0312
......
1.4G
........................................
None
62
None
Forbidden
75 kg
02
25
Cartridges, signal
1.4S UN0405
......
1.4S
........................................
None
62
None
25 kg
100 kg
01
25
Cartridges, starter, jet engine, see
Cartridges, power device
Cases, cartridge, empty with primer
1.4S UN0055
......
1.4S
50 63
62
None
25 kg
100 kg
01
25
Cases, cartridges, empty with prim-
er
1.4C UN0379
......
1.4C
50 None
62
None
Forbidden
75 kg
02
25
Cases, combustible, empty, without
primer
1.4C UN0446
......
1.4C
........................................
None
62
None
Forbidden
75 kg
02
25
Cases, combustible, empty, without
primer
1.3C UN0447
......
1.3C
........................................
None
62
None
Forbidden
Forbidden
03
25
Casinghead gasoline see Gasoline
194
49 CFR Ch. I (10–1–23 Edition)
§
172.101
§ 172.101 H
AZARDOUS
M
ATERIALS
T
ABLE
—Continued
Sym-
bols
Hazardous materials descriptions
and proper shipping names
Hazard
class or
Division
Identi-
fication
Numbers
PG
Label
Codes
Special provisions
(§ 172.102)
(8)
(9)
(10)
Vessel
stowage
Packaging
(§ 173.***)
Quantity limitations
(see §§ 173.27 and
175.75)
Loca-
tion
Other
Excep-
tions
Non-bulk
Bulk
Passenger
aircraft/rail
Cargo air-
craft only
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
A W
Castor beans or Castor meal or
Castor pomace or Castor flake
9 UN2969
II
None
IB8, IP2, IP4, T3, TP33 155
204
240
No limit
No limit
E
34, 40,
44, 122
Catecholborane
................
......
A210
G
Caustic alkali liquids, n.o.s.
8 UN1719
II
8
B2, IB2, T11, TP2, TP27 154
202
242
1 L
30 L
A
29, 52
III
8
IB3, T7, TP1, TP28 154
203
241
5 L
60 L
A
29, 52
Caustic potash, see Potassium hy-
droxide etc
Caustic soda, (etc.) see Sodium hy-
droxide etc
Cells, containing sodium
4.3 UN3292
......
4.3
189
189
189
25 kg
No limit
A
Celluloid, in block, rods, rolls,
sheets, tubes, etc., except scrap
4.1 UN2000
III
4.1
420 151
213
240
25 kg
100 kg
A
Celluloid, scrap
4.2 UN2002
III
4.2
IB8, IP3 None
213
241
Forbidden
Forbidden
D
Cement, see Adhesives containing
flammable liquid
Cerium, slabs, ingots, or rods
4.1 UN1333
II
4.1
IB8, IP2, IP4, N34,
W100
151
212
240
15 kg
50 kg
A
13, 74,
91,
147,
148
Cerium, turnings or gritty powder
4.3 UN3078
II
4.3
A1, IB7, IP2, IP21, T3,
TP33, W31, W40
151
212
242
15 kg
50 kg
E
13, 52,
148
Cesium or Caesium
4.3 UN1407
I
4.3
A7, A19, IB4, IP1, N34,
N40, W31
None
211
242
Forbidden
15 kg
D
13, 52,
148
Cesium nitrate or Caesium nitrate
5.1 UN1451
III
5.1
A1, A29, IB8, IP3, T1,
TP33
152
213
240
25 kg
100 kg
A
D
Charcoal briquettes, shell,
screenings, wood, etc.
4.2 NA1361
III
4.2
IB8, T1, TP33 151
213
240
25 kg
100 kg
A
12
Charges, bursting, plastics bonded
1.1D UN0457
......
1.1D
........................................
None
62
None
Forbidden
Forbidden
03
25
Charges, bursting, plastics bonded
1.2D UN0458
......
1.2D
........................................
None
62
None
Forbidden
Forbidden
03
25
Charges, bursting, plastics bonded
1.4D UN0459
......
1.4D
........................................
None
62
None
Forbidden
75 kg
02
25
Charges, bursting, plastics bonded
1.4S UN0460
......
1.4S
347 None
62
None
25 kg
100 kg
01
25
Charges, demolition